Biochemistry Flashcards

1
Q

What do sugars, fatty acids, amino acids, and nucleotides turn into

A

polysaccharides
fats/membrane lipids
proteins
nucleic acids

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2
Q

what are some properties of carbohydrates

A

hydrophilic, polar, water soluble

n(CH20)

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3
Q

What are monosaccharides classified into

A

Aldoses or ketoses

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4
Q

what is the cyclic structure called when going from linear to cyclic form

A

pyranose

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5
Q

what is the most naturally occurring sugar

A

D-isomers

D-glucose (dextrose) can be metabolised and not L-glucose

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6
Q

what is meant by an epimer

A

stereoisomer that differs in configuration at a single asymmetric/chrial carbon

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7
Q

what is meant by anomeric carbon

A

anomeric carbon - C1 in the ring structure

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8
Q

what happens when a glycosidic bond forms

A

the alpha and beta configurations are locked, so can no longer switch

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9
Q

what are the 3 main types of lipids

A

Triacylglycerols - hydrophobic so stored in fat droplets in cells
Glycerophospholipids - Amphipathic
Steroids - Cholesterol inserts into membrane to regulate fluidity

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10
Q

which amino acids are positive and negative (both polar)

A

positive - lysine, arginine, histidine

negative - aspartate, glutamate

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11
Q

which amino acids are uncharged and polar

A

tyrosine, serine, threonine, asparagine, glutamine

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12
Q

which amino acids are non polar

A
glycine
alanine
valine
leucine
isoleucine
proline
phenylalanine
tryptophan
cysteine
methionine
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13
Q

what is meant by enthalpy change

A

the sum of energy released when forming bonds, and required to break bonds

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14
Q

which reactions are more likely to occur. - or + enthalpy change

A

-ve enthalpy change more likley to occur

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15
Q

what is the 2nd law of thermodynamics

A

all processes must increase the entropy of the universe

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16
Q

what is meant by entropy change

A

level of disorder

17
Q

what is ‘Gibbs free energy’

A

useful energy available from a reaction

18
Q

what is the formula for Gibbs free energy

A

delta G = delta H - T delta S

19
Q

what is the difference between an exergonic and an endergonic reaction

A

exergonic reaction - change in free energy is -ve - reaction can occur spontaneously
endergonic reaction - change in free energy is +ve - reaction cannot occur spontaneously

20
Q

what is an issue, that we don’t know about a spontaneous reaction

A

we dont know about the rate of reaction ie. high Ea