Bio+chem+phy Flashcards
What is Avogadro’s number?
6.02 x 10^23
What does Avogadro’s number tell us?
the number of particles in a mole of a substance
Which isotope are all other particles compared to when determining their relative mass?
Carbon - 12
What order do the orbitals fill in (up to the end of the third energy level)?
1s2s2p3s3p4s3d
What order do we write the orbitals when they have electrons in them?
1s2s2p3s3p3d4s
What are the properties of metals?
Good conductors of heat and electricity, high melting and boiling points, malleable, ductile
Describe the structure of a metal
A giant lattice with layers of positive ions surrounded by delocalised electrons
Define the term ‘first ionisation energy’
The energy required to remove one mole of electrons from one mole of gaseous atoms
Which factors affect the first ionisation energy?
Nuclear charge, shielding, atomic radius, spin-pair repulsion
What shape are s-orbitals?
Spherical
What shape are p-orbitals?
Dumb - bell shaped
Why is the first ionisation energy always endothermic?
energy is required to break the attraction between the nucleus and outermost electron
What are the three types of subshell or orbital?
S - P - d
How many electrons can fit in a subshell or orbital?
2
How many electrons can fit in the first energy level or shell?
2
How many electrons can fit in the second energy level or shell?
8
How many electrons can fit in the third energy level or shell?
18
How many s-orbitals are there in each energy level?
1
How many p-orbitals are there in the second and third energy level?
3 - each
How many d-orbitals are there in the third energy level?
1
How is the spin of two electrons in an orbital related? Why?
Opposite, to minimise repulsion
Why do electrons fill orbitals singly first, before pairing up?
To minimise repulsion
What is a ‘delocalised’ electron?
An electron that can move
What is a lattice?
regular, repeating, 3D structure
Define ‘metallic bonding’
the electrostatic attraction between positive ions and delocalised electrons
Why are metals good conductors of heat?
their delocalised electrons move around and pass on energy whenever they collide with another electron or positive ion in the lattice
Why are metals good conductors of electricity?
delocalised electrons can move and carry charge through the structure