behavior and uses of metals Flashcards
stage 1
coke burns to give co2, blast of hot air starts the coke burning
stage 1 reaction
c + o2 - co2
carbon is oxidised, highly exothermic, heat given out heats furnace
stage 2
co2 is reduced to carbon monoxide, co2 reacts with more coke
stage 2 reactions
c + co2 - 2co
carbon is reduced, endothermic, takes heat from furnace
stage 3
carbon monoxide reduces iron III oxide to iron, extraction of metal occurs
stage 3 reactions
fe2o3 + 3co - 2fe +3co2
iron oxide is reduced, iron trickles to the bottom, co is the reducing agent, co is reduced
stage 4
slag is formed, calcium silicate forms slag which runs down the furnace and floats on the iron
stage 4 reactions
caco3 -heat- cao + co2
limestone breaks down in the heat of the furnace- thermal decomposition
cao + sio2 - casio3
calcium oxide reacts with sand, main impurity in iron ore. sand is mostly silicon
alloy
mixture of a metal with at least one other element
alloy benefits
change properties to make it more useful
brass
- copper and zinc
- used for ornaments, instruments and door knobs
- hard, doesnt corrode and attractive
stainless steel
- iron, carbon, chromium and nickel
- used for cutlery and construction equipment
- hard, doesnt corrode and attarctive
rusting
name given to the corrosion of iron (breakdown). iron reacts with water and oxygen to give hydrated iron III oxide
rusting formula
4fe + 3o2 + 4h2o - 2feo3 + 2h2o
prevention
covering the metal
sacrificial protection
covering the metal
- paint
- grease
- plastic
- another metal
sacrificial protection
cover the metal with zinc so it corrodes instead of iron or steel. this provides a layer of protection. zinc will corrode and the corrosion can be removed for it to corrode again
aluminum
placed between zinc and magnesium on the reactivity series, ahead of carbon but unreactive. aluminum reacts readily with oxygen forming hard impenetrable oxide layer protecting the aluminum from further reaction
displacement reactions
a more reactive metal will also displace a less reactive metal from a solution which contains the less reactive metal. the more reactive metal loses electrons to form positive ions.
characteristics chemical properties of metals
a reactive metal is one that readily loses its valancy electrons to form compounds
reactivity series
potassium
sodium
calcium
magnesium
aluminum
carbon
zinc
iron
tin
lead
hydrogen
copper
silver
gold
platinum
metal extraction from ores
only a few unreactive metals are found ‘native’ i.e in their pure metal form. other metals are found in compounds and need to be extracted. this involves the reduction of the metal ions to give the metal
reduction may occur via
- electrolysis
- reaction with carbon
reaction with carbon
carbon will reduce metal oxides to the metal, if the metal is less reactive than carbon on the reacitivity series
metal extractions
- carbon is used as a reference point to determine the method of extraction
- method of extraction is linked strongly to the reactivity series
- metals above carbon in the reactivity series must be extracted from their ores by electrolysis
- metals below carbon are reduced by carbon
- the least reactive metals occur in their native states and are separated by physical processes not chemical reactions