Basic concepts of Organic Chemistry Flashcards

1
Q

How do you name organic compounds?

A
  1. Find the longest carbon chain of the molecules
  2. The functional group tells us the ending of the molecule
  3. Number the carbon chain so that the functional group sit on the lowest possible carbon number
  4. Make a not of the carbon attached to the functional group and place the number before the suffix
  5. Any side chains and less important functional groups are written as prefixes
  6. If there is more than 1 identical functional group, put di, tri or tetra
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2
Q

Define general formula

A

An algebraic formula that can describe any member of a homologous series of compounds

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3
Q

Define structural formula

A

The arrangement of atoms in a molecule without showing all the bonds

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4
Q

Define empirical formula

A

The simplest whole number ratio of atoms of each element in a compound

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5
Q

Define molecular formula

A

The actual number of atoms in an element

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6
Q

Define displayed formula

A

Shows the arrangement of atoms showing all the bonds and atoms in the molecule

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7
Q

Define skeletal formula

A

Shows the bonds of the carbon skeleton only (functional group are only shown)

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8
Q

Define Homologous series

A

A family of organic compounds that have the same general formula and similar chemical properties

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9
Q

What are the homologous series?

A
  • Alkanes
  • Alkenes
  • Alcohols
  • Aldehydes
  • Ketons
  • Carboxylic Acid
  • Haloalkanes
  • Cycloalkanes
  • Esters
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10
Q

Define functional group

A

The group of atoms that is responsible for the characteristic reactions of a compound

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11
Q

Define an alkyl group

A

A hydrocarbon fragment with general formula CnH2n+1

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12
Q

Define an aliphatic compound

A

A compound containing carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings

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13
Q

Define an alicyclic compound

A

An organic compound that contains carbon and hydrogen joined together in an non-aromatic ring

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14
Q

Define an aromatic compound

A

An organic compound that contains a benzene ring

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15
Q

Define an unsaturated hydrocarbon

A

A hydrocarbon with carbon-carbon double bonds

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16
Q

Define a saturated hydrocarbon

A

A hydrocarbon with single carbon-carbon bonds

17
Q

Define structural isomers

A

Compounds with the same molecular formula but different structural formula

18
Q

Define chain isomers

A

Compounds with the same molecular formula but different arrangement of carbon skeleton

19
Q

Define positional isomers

A

Compounds with the same molecular formula but different position of the functional group on the carbon skeleton

20
Q

Define functional group isomers

A

Compounds with the same molecular formula but different functional group

21
Q

Define homolytic fission

A
  • The bond breaks evenly and each atom receives one electron from the bonded pair
  • Two uncharged radicals are formed
22
Q

Define heterolytic fission

A
  • The bond breaks unevenly with one of the bonded atoms receives both electrons from the bonded pair
23
Q

What is a radical?

A
  • Radicals are very reactive and have an unpaired electron
24
Q

What do we use to show the movement of electrons?

A
  • Curly arrows