Atoms and the Periodic Table Flashcards

1
Q

Explain atomic mass.

A

The are the average masses calculated based on the mass and % abundance of the naturally occurring stable isotopes.

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2
Q

Where was Dmitri Medelev born?

A

Siberia, Russia.

He invented the periodic table.

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3
Q

What determines the identity of an atom?

A

The number of protons in its nucleus.

Also called the elements atomic number.

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4
Q

What comprises almost 100% of an atoms volume?

A

The electron cloud.

If the nucleus was a grain of rice, the electron cloud would be the size of a football stadium.

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5
Q

True or False:
A proton is attracted to a neutron.

A

False.

Neutrons don’t have an electric charge.

A proton is attracted to an electron.

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6
Q

True or False:
The nucleus contains virtually all the mass of an atom.

A

True.

Electrons are so light they aren’t counted for.

Protons and neutrons both have a mass of 1.

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7
Q

True or False:
Protons and electrons have opposing charges.

A

True.

Opposing charges attract one another.

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8
Q

State the subatomic particle that matches the description:

  1. Has virtually no mass.
  2. Has a positive charge (+1).
  3. Is electrically neutral.
  4. Particles that make up most of the nucleus.
A
  1. Electrons.
  2. Protons.
  3. Neutrons.
  4. Protons and neutrons.
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9
Q

Gallium has 2 isotopes. 60.4% is Ga-69 (mass = 68.9257 amu), and 39.6% is Ga-71 (mass = 70.9248 amu).

Calculate the atomic weight for gallium.

A

Rounded and proper significant figures.

69.7 amu

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10
Q

If an atom has 28 protons and A = 60.

Identify:

How many electrons does it have?
How many neutrons does it have?
What element is the atom from?

A

It has 28 protons and electrons.

If A = 60 neutrons = ?

60 - 28 = 32.

It would have 32 neutrons.

of protons = atomic # … therefore the element is nickel.

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11
Q

Which atom is bigger, Na or Cl?

A

Na is bigger.

Nuclear charge rises from left to right in a period.

Since the electronegativity increases, as does the attraction to the valence electrons. This causes the atoms size to shrink.

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12
Q

What atom is larger, Rb or Na?

A

Rb is larger.

Generally the atomic radius increases as we move down the groups.

Rb is below Na, thus we would expect it to be larger.

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13
Q

Place the elements in order of decreasing atomic size:

Cl, Br, I.

A

I, Br, Cl.

Because I is the lowest, it would actually be the biggest.

Bottom left biggest, the more up an right you move, the smaller the atoms get.

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14
Q

Which group on the periodic table are highly reactive, silvery, soft metals?

A

Group 1 (Alkali metals).

Groups = columns.

Periods = Rows

Remember: periods have to have a period at the end like a sentence.

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15
Q

Which group on the periodic table are colorful and reactive non-metals?

A

Group 7 (Halogens).

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16
Q

Which group on the periodic table are chemically invert, colorless gasses?

A

Noble gasses.

They have no reactions.

Ne, He, and Ar do not combine with anything.

17
Q

Write out the electron configuration of magnesium.

A

Mg = 12 electrons.

1s2, 2s2, 2p6, 3s2.

or… Mg = [Ne] 3s2.

Ne is the preceding noble gas.

18
Q

Write the electron configuration of phosphorus (z = 15).

A

1s2, 2s2, 2p6, 3s2, 3p3.

or… [Ne] 3s2, 3p3.

19
Q

What is the maximum # of electrons that occupy the 4th shell?

A

32 electrons.
________________________
1st shell = 2 electrons
2nd shell = 8 electrons
3rd shell = 18 electrons
4th shell = 32 electrons

20
Q

What is the maximum electrons that can occupy the 3d shell?

A

10 electrons because each orbital can carry 2 electrons, and d have 5 orbitals.
___________________
s = 1 orbital; 2 max. electrons
p = 3 orbitals; 6 max. electrons
d = 5 orbitals; 10 max. electrons
f = 7 orbitals; 14 max. electrons

21
Q

What is the electron configuration of carbon?

A

C (z = 6)

1s2, 2s2, 2p2.
or
[He] 2p2.

22
Q

Which element has the following electron configuration?

1s2, 2s2, 2p6, 3s2.

A

Magnesium.

By counting how many electrons are on each energy level, you can use that electron number to find the atomic number.

23
Q

Which element group would be represented by the # of dots on the Lewis-dot diagram.

  1. 6 dots.
  2. 3 dots.
  3. 2 dots.
  4. 7 dots.
  5. 8 dots.
  6. 1 dot.
A
  1. 6 dots = Group 6A
  2. 3 dots = Group 3A
  3. 2 dots = Group 2A (alkali earth metals)
  4. 7 dots = Group 7A (halogens)
  5. 8 dots = Group 8A (noble gasses)
  6. 1 dot = Group 1A (alkali metals)
24
Q

Amphetamine, a commonly abused drug, is comprised of nine atoms of carbon, 13 atoms of hydrogen, and one atom of nitrogen.

How would you write the chemical formula of amphetamine?

A

C9H13N.

25
Q

An s-block element in the 5th period is:

A) Mo
B) Ag
C) As
D) Y
E) Sr

A

E) Sr

The s-block is group 1A and 2A.

To know the period count the rows from top to bottom beginning with the row H + He.

26
Q

An oxygen atom with a mass number of 18 has:

A) 8 protons, 8 electrons.
B) 10 protons, 8 neutrons.
C) 8 protons, 10 neutrons.
D) 8 neutrons, 10 protons.
E) 2 of these answers are correct.

A

E) 2 of these answers are correct.

A) 8 protons, 8 electrons.
C) 8 protons, 10 neutrons.

27
Q

Which element corresponds with the following electron configuration?

1s2, 2s2, 2p6, 3s2, 3p2.

A

Silicon.

Count the superscript to find how many electrons it has, then b/c p+ = e- = atomic # (z) …
the electron number is the z. (assuming its a neutral atom, not an ion).

28
Q

True or False:
Density = specific gravity.

A

True.

Because water is 1g/mL at normal temperatures, density = specific gravity.

Specific gravity has no units because they cancel out = g/mL.

29
Q

What are the units used for specific gravity?

A

Trick question! - There are no units for specific gravity because they cancel out.

Specific gravity = density g/mL /density of water 1g/mL.

30
Q

At normal temperatures, what is the density of water?

A

1 g/mL.

31
Q

If an element has 7 valence electrons, which group must it belong to?

A

It would belong to group 7, halogens.

of valence electrons = group number.

32
Q

How many orbitals does the ‘p’ subshell have?

What is the maximum electron number for the ‘p’ subshell?

A

The ‘p’ subshell has:

3 orbitals and can hold a maximum of 6 electrons.

33
Q

Which are the most reactive?

A) Halogens.
B) Noble gasses.
C) Alkali metals.
D) Alkali earth metals.
E) Transition metals.

A

C) Alkali metals.

Na is not found in nature because it explodes when it reacts with air or water.

34
Q

Which elements correspond to the ‘d-block’?

A

Transition metals.

Ex. Ti (z = 22).
1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d2.
or [Ar] 4s2, 3d2.

35
Q

Which elements correspond to the ‘s-block’?

A

Group 1A - 2A.

The valence shell of these elements will finish with a s orbital.

Example: H (z = 1) = 1s1.

36
Q

Which elements correspond to the ‘p-block’?

A

Elements in group 3A - 8A.

These elements electron configuration will have the p orbital as its valence shell.

Example: O (z = 8). 1s2, 2s2, 2p4.

37
Q

Why were noble gasses not known at the time of Mendelev?

A

Elements were discovered based on reactivity.

It was hard for scientists to work with them because they are so unreactive.