Atoms and amount of susbtance Flashcards
Charges on subatomic particles
proton - positive charge
neutron - neutral
electron - negative charge
charge on proton is equal but opposite to electron charge
masses of subatomic particles
proton - 1
neutron - 1
electron 1/1840 (negligible)
isotope
atoms of the same element with different number of neutrons so different masses
isotopes and chemical reactions
different isotopes of same element have same number of electrons
number of neutrons has no effect on reactions
therefore isotopes react in the same way
ion
charged atom with different number of electrons to protons
relativic atomic mass
weighted mean mass of an atom of an element relative to 1/12th of the mass of an atom of carbon-12
mole
amount of substance that contains 6.02 x 10^(23) particles (avogadro constant - number of particles in a mole of carbon 12)
molar mass
mass in grams in each mole of a substance
molecular formula
number of atoms of each element in a molecule
empirical formula
simplest whole number ratio of atoms of each element in a compound
ideal gas equation
pv=nRT
P in Pa so 1kpa = 1000pa so x1000
T in K so 1C = 273K so +273
V is in m3 1cm3 = 0.000001 x10-(^6)
What is molecular ion peak?
- mass of whole molecule in sample that hasn’t been fragmented
- usually an extremely small percentage with w higher mass than the rest
What is the M+1 peak?
- Higher mass by one that ‘molecular ion peak’ due to the isotope of an atom in molecule
What are the uses of mass spectrometry?
- identifies unknown compounds
- determines the abundance of isotopes in an element
- more knowledge about structure and chemical properties of molecules
Why might percentage yield be less than 100% (4)
Reaction might not be complete
Other unwanted reactions happen
Product lost in purification
Starting material may be impure