atomic structure/electrons Flashcards
democritus
atomos: undivided
could not be divided, created, or destroyed
aristotle
four elements: fire, water, air, and earth
lavoisir
father of modern chemistry
law of conservation of mass
33 elements
proust
law of definite proportions
john dalton
law of multiple proportions: the mass ratio for elements can be expressed in small, whole numbers
first table elements by mass
dalton’s atomic theory
daltons atomic theory
- all matter is made up of atoms
- all atoms of a given element are identical in mass and properties
- compounds are formed by a combination of two or more atoms
- a chemical reaction is a rearrangement of atoms
j.j. thomson
cathode ray experiment in 1897: electrons have negative charge, charge to mass ratio, and both + and - particles are present
plum pudding model in 1909
robert millikan
“oil drop experiment” in 1908
used to calculate mass of electron
ernest rutherford
gold foil experiment in 1911
nuclear atomic model in 1910: the nucleus is dense and mostly empty space
niels bohr
modern model of the atom: dense nucleus surrounded by orbiting electrons
erwin shrodinger
proposes wave mechanical model of electron
james chadwick
nobel peace prize for discovering neutron
max planck (and equation)
said energy is quantized and can only be absorbed in small whole number multiplies related to frequency
e=hv defines one quantum/photon of energy
einstein
emr is a stream of photons (little packets of energy) with mass and energy
de broglie
emr has wave and particle characteristics
bohr
calculated the wavelength of a photon emitted by hydrogen electron
electromagnetic
waves of electric and magnetic fields at right angles to each other
radiation
menergy that travels and spreads as it goes out (radiates out from charged particles)
electromagnetic radiation spectrum
radio waves, microwaves, infrared, ultraviolet radiation, x-rays, and gamma rays
heisenberg uncertainty principle
impossible to know the exact location and momentum of an electron at the same time so it ruled out define locations for electrons
wavelength
distance between any point on a wave and the corresponding point on the next wave
frequency
how many wavelengths pass a fixed point in a given time
speed of propagation
(c) rate at which wave travels through space
as frequency increases, wavelength decreases
photoelectric effect
einstein
metals emit electrons when struck by light
particle vs wave
particle is localized and wave is delocalized
particle is matter and wave is energy
wave-particle daulity
light can show wave or particle behavior
atomic emission spectra
each element has a unique emission spectra
rydberg formula for hydrogen
full spectrum of emission from hydrogen
bhor atomic theory and its flaws
introduced quantum concept into atomic theory
predicted emission spectrum of hydrogen
only worked for hydrogen and other one-electron systems
quantum mechanical model
behavior of the electron described by a set of allowed wave functions (Ψ) called orbitals
each wave function has definite energy
electron moves between orbitals by absorbing/emitting quantum of energy equal to the energy difference between the states (similar to bohr model).