atomic structure/electrons Flashcards

1
Q

democritus

A

atomos: undivided

could not be divided, created, or destroyed

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2
Q

aristotle

A

four elements: fire, water, air, and earth

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3
Q

lavoisir

A

father of modern chemistry
law of conservation of mass
33 elements

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4
Q

proust

A

law of definite proportions

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5
Q

john dalton

A

law of multiple proportions: the mass ratio for elements can be expressed in small, whole numbers
first table elements by mass
dalton’s atomic theory

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6
Q

daltons atomic theory

A
  1. all matter is made up of atoms
  2. all atoms of a given element are identical in mass and properties
  3. compounds are formed by a combination of two or more atoms
  4. a chemical reaction is a rearrangement of atoms
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7
Q

j.j. thomson

A

cathode ray experiment in 1897: electrons have negative charge, charge to mass ratio, and both + and - particles are present
plum pudding model in 1909

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8
Q

robert millikan

A

“oil drop experiment” in 1908

used to calculate mass of electron

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9
Q

ernest rutherford

A

gold foil experiment in 1911

nuclear atomic model in 1910: the nucleus is dense and mostly empty space

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10
Q

niels bohr

A

modern model of the atom: dense nucleus surrounded by orbiting electrons

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11
Q

erwin shrodinger

A

proposes wave mechanical model of electron

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12
Q

james chadwick

A

nobel peace prize for discovering neutron

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13
Q

max planck (and equation)

A

said energy is quantized and can only be absorbed in small whole number multiplies related to frequency
e=hv defines one quantum/photon of energy

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14
Q

einstein

A

emr is a stream of photons (little packets of energy) with mass and energy

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15
Q

de broglie

A

emr has wave and particle characteristics

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16
Q

bohr

A

calculated the wavelength of a photon emitted by hydrogen electron

17
Q

electromagnetic

A

waves of electric and magnetic fields at right angles to each other

18
Q

radiation

A

menergy that travels and spreads as it goes out (radiates out from charged particles)

19
Q

electromagnetic radiation spectrum

A

radio waves, microwaves, infrared, ultraviolet radiation, x-rays, and gamma rays

20
Q

heisenberg uncertainty principle

A

impossible to know the exact location and momentum of an electron at the same time so it ruled out define locations for electrons

21
Q

wavelength

A

distance between any point on a wave and the corresponding point on the next wave

22
Q

frequency

A

how many wavelengths pass a fixed point in a given time

23
Q

speed of propagation

A

(c) rate at which wave travels through space

as frequency increases, wavelength decreases

24
Q

photoelectric effect

A

einstein

metals emit electrons when struck by light

25
Q

particle vs wave

A

particle is localized and wave is delocalized

particle is matter and wave is energy

26
Q

wave-particle daulity

A

light can show wave or particle behavior

27
Q

atomic emission spectra

A

each element has a unique emission spectra

28
Q

rydberg formula for hydrogen

A

full spectrum of emission from hydrogen

29
Q

bhor atomic theory and its flaws

A

introduced quantum concept into atomic theory
predicted emission spectrum of hydrogen
only worked for hydrogen and other one-electron systems

30
Q

quantum mechanical model

A

behavior of the electron described by a set of allowed wave functions (Ψ) called orbitals
each wave function has definite energy
electron moves between orbitals by absorbing/emitting quantum of energy equal to the energy difference between the states (similar to bohr model).