Atomic Structure & Chemical Bonding Flashcards

1
Q

Define elements.

A

simplest substances, are made up from simple particles.

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2
Q

Define molecules.

A

more than one atom bonded together, can be the same type of atoms or different atoms.

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3
Q

Define compounds.

A

combinations of different types of atoms, pure substance which consists of two or more elements chemically combined.

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4
Q

Define atoms.

A

smallest part of an element that can exist chemically but not the smallest particles, (made up of protons, neutrons & electrons

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5
Q

Define atomic no.

A

smaller no.

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6
Q

Define isotopes.

A

atoms of same element with different no. of neutrons but same no. of protons.

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7
Q

Define electrons.

A

subatomic particles with a -1 charge, demonstrate wave/particle duality.

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8
Q

What happens when an atom absorbs energy?

A

e- jumps from ground state to excited state (up an energy level/s).

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9
Q

Give Schrodingers theory of the H atom.

A

properties of waves used to explain behaviour of e- in atoms

  • an e- in a particular orbit is described by a wavefunction
  • this model shows the nucleus surrounded by a cloud of e-
  • regions of space referred to as e- or atomic orbitals where there is a high probability of finding an e-.
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10
Q

How are e- arranged>

A

atoms are arranged in successive principle energy levels.

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11
Q

As principle quantum no. increases, e- density…

A

decreases.

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12
Q

Give the Pauli exclusion.

A

each orbital has max 2 e- with antiparallel spins.

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13
Q

Give Hund’s rule.

A

max multiplicity, e- fill set a of degenerate energy orbitals by keeping their spins parallel.

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14
Q

Give the Aufbau principle.

A

to populate orbitals for a given atom, start at lowest energy orbital and work upwards.

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15
Q

What configuration does an atom in the ground state adopt?

A

configuration with the greatest no. of unpaired e-.

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16
Q

Describe noble gases.

A
  • stable & inert
  • monatomic
  • do not normally form bonds with other elements
  • do not need to gain, lose or share e- to become more stable
  • fulfill Lewis Octat rule
17
Q

Chemical bonds are formed between atoms with…

A

less than 8 e- in their valence shell, in order to make them more stable and fulfil the octat rule.

18
Q

What are chemical bonds made of?

A

e-

19
Q

Atoms must _ to form bonds.

A

atoms must collide with each other to form bonds.

20
Q

Give the 2 types of e- in an atom.

A

Core & valence.

21
Q

Define the 2 main chemical bonds.

A

-ionic
electrostatic attraction that forms between two oppositely charged ions. Ionic compounds form giant 3D lattices.
-covalent
electrostatic attraction between shared pair of electrons between atoms and the positive nuclei of those atoms. Can have up to 3 pairs of e- shared between 2 atoms.

22
Q

Define electronegativity.

A

Ability of an atom to draw the e- from a bonding pair towards its nucleus.

23
Q

What determines whether a bond is ionic or covalent?

A

electronegativity.

24
Q

Give the features that produce a high electronegativity.

A
  • higher nuclear charge
  • small atomic radius
  • low e- shielding
25
Q

Electronegativity is a periodic property, and so depends on…

A
  • how many protons
  • how far valence electrons are form nucleus
  • electron shielding
26
Q

Give the value of electronegativity difference for ionic bonding.

A

> 1.7

27
Q

Give the value of electronegativity difference for covalent bonding.

A

<1.7