Atomic Structure And Isotopes Flashcards

1
Q

What was stated in Dalton’s Atomic theory?

A

Atoms are tiny particles made of elements
Atoms cannnot be divided
All the atoms in an element are the same
Atoms of one element are different to those of other elements.

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2
Q

What did Thompson discover about electrons?

A

They have a negative charge
They can be deflected by magnet and electric field
They have a very small mass

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3
Q

Explain the plum pudding model

A

Atoms are made up of negative electrons moving around a sea of positive electrons

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4
Q

What was Rutherford proposal after the gold leaf experiment?

A

Most of the mass and positive charge of the atom are in the nucleus
Electrons orbit the nucleus
Most of the atoms volume is in the space between the electrons and the nucleus
Overall positive and negative charges must balance

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5
Q

Explain the current model of the atom

A

Protons and neutrons are found in the nucleus
Electrons orbit in shells.
Nucleus is tiny compared to the total volume of the atom
Most of the atoms mass is in the nucleus
Most of the atom is empty space between the nucleus and the electrons

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6
Q

What is the charge of a proton, neutron and electron.

A

Proton is +1
Neutron is 0
Electron is -1

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7
Q

What particle has the same mass as a proton?

A

Neutron and they have a mass of 1

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8
Q

What is the mass of an electron?

A

1/1836

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9
Q

Define isotope

A

Atoms of the same element with different number of neutrons.

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10
Q

Why do different isotopes of the same element react in the same way?

A

Neutrons have no impact on chemical reactivity

Reactions involve electrons, isotopes have the same number of electrons in the same arrangement.

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11
Q

What are ions?

A

Charged particles that are formed when an atom loses or gains electrons.

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12
Q

What are the charges of a) an atom that has gained electrons. And b) an atom that loses its electrons

A

a) negative, an anion

b) positive, a cation

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13
Q

What is the unit used to measure atomic masses called?

A

Unified atomic mass unit, u

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14
Q

Define relative atomic mass

A

The weighted mean mass of an atom of an element compared with one twelfth of the mass of an atom of carbon-12

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15
Q

What is the unit of relative atomic mass

A

No units

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16
Q

Define relative isotopic mass

A

The mass of a atom of an isotope compared with one twelfth of the mass of an atom of carbon-12

17
Q

What two assumptions are made when calculating mass number?

A

Contribution of the electron is neglected

Mass of both neutron and proton is taking as 1

18
Q

What are the uses of mass spectrometry?

A

Identify unknown compounds
Find relative abundance of each isotope of an element
Determine structural information

19
Q

How does a mass spectrometer work?

A

The sample is made into positive ions
They pass through the apparatus and are separated according to mass to charge ratio
A computer analyses the data and produces a mass spectrum.

20
Q

How is the group number related to the number of electrons?

A

Group number= number of electrons in the outer shell.

21
Q

Do metals usually gain or lose electrons?

A

Lose electrons

non-metals generally gain electrons

22
Q

Which are the 4 elements that don’t tend to form ions and why?

A

The elements are beryllium, boron, carbon and silicon.

As it requires a lot of energy to transfer outer shell electrons.

23
Q

What are molecular ions?

A

Covalently bonded atoms that loses or gain electrons.

24
Q

What is the charge of an ammonium ion?

A

+1 —> NH4 +

25
Q

What is the charge of a hydroxide ion?

A

-1 —> OH-

26
Q

What is the charge of a nitrate ion?

A

-1 —> NO3-

27
Q

What is the charge of a carbonate ion?

A

-2 —> CO3 2-

28
Q

What is the charge of a sulphate Ion?

A

-2 —> SO4 2-

29
Q

What is an empirical formula?

A

Simplest whole number ratio of atoms of each element present in a compound

30
Q

How to calculate empirical formula?

A

Divide the amount of each element by its molar mass
Divide the answers by the smallest value obtained
If there is a decimal, divide by a suitable number to make it into a whole number.