Atomic Structure Flashcards
Dalton
- early 1800s
- said atoms are tiny solid spheres
- believed atoms couldn’t be broken down
J. J. Thompson
- 1897
- discovered the electron using cathode ray experiments
- proposed the plum pudding model
What is the plum pudding model
A ball of positive charge with negative electrons scattered through it
Rutherford
- 1909
- carried out the alpha scattering experiment
- proposed the nuclear model
Alpha scattering experiment
- fired alpha particles at thin gold foil
- most went straight through - atom is mostly empty space
- some deflected - nucleus is small and positively charged
- a few bounced straight back - nucleus must be very dense
Nuclear model
Small dense nucleus surrounded by electrons
Bohr
- 1913
- suggested electrons orbit the nucleus in fixed energy levels (shells)
- this matched experimental results and explained chemical behaviour
Chadwick
- 1932
- discovered the neutron, a particle in the nucleus with no charge but similar mass to a proton
Nucleus
- tiny - radius of about 1 x 10^-14m
- contains protons +1 and neutrons 0
- has the most mass
Electrons
- orbit the nucleus in shells
- negatively charged (-1), very small mass
Atoms
- have nucleus and electrons
- mostly empty space
- they’re neutral as theres the same number of protons and electrons
Proton relative mass and charge
- relative mass: 1
- charge: +1
Neutron relative mass and charge
- relative mass: 1
- charge: 0
Electron relative mass and charge
- relative mass: very small
- charge: -1
What is an isotope
- atoms of the same element (same protons) with different numbers of neutrons
- example: carbon-12 vs carbon-14
- some isotopes are unstable - radioactive decay
Mass number
Protons + neutrons
Atomic number
Number of protons
Radioactive decay
- random process - can’t predict when a specific nucleus will decay
- decay happens to make the nucleus more stable
- releases radiation: changes atomic/mass number
Alpha particles
- 2 protons + 2 neutrons (helium nucleus)
- low penetration
- high ionising power
- blocked by paper/skin
Beta particles
- high-speed electron
- neutron= proton + e-
- medium penetration
- medium ionising power
- blocked by thin aluminium
Gamma particles
- EM wave
- no mass or charge
- high penetration
- low ionising power
- blocked by thick lead/concrete
What is half-life
- time it takes for half of the radioactive nuclei in sample to decay
- OR for activity (decays per second) to halve
- measured in Becquerels (Bq)
Long half life
Decays slowly, remains radioactive for a long time
Short half life
- rapid decay, but dangerous in short term
What is radioactive decay
- The random process by which an unstable atomic nucleus loses energy by emitting in radiation in order to become more stable
- it happens spontaneously - we cannot predict exactly when a particular atom will decay
- the process continues until the atom reaches a stable form
Irradiation
- definition: exposure to radiation, but no material contact
- example: being near a gamma source
- protection: shielding, limit exposure
Contamination
- definition: radioactive material gets on/ in you or an object
- example: swallowing/inhaling radioactive dust
- protection: gloves, suits, tongs
What happens to irradiated objects and contaminated materials
- irradiated objects do not become radioactive
- contaminated materials emit radiation until cleaned/decayed
Uses of radiation
- Medical tracers
- radiotherapy
- sterilisation
- smoke alarms
Medical tracers
- beta or gamma emitters used
- short half life so it doesn’t stay radioactive
- used to track organ function (e.g., kidneys, thyroid)
Radiotherapy
- gamma rays used to kill cancer cells
- focused to avoid healthy tissue as much as possiblee
Sterilisation
- gamma rays used to kill bacteria on medical equipment or food
Smoke alarms
- use alpha emitters
- alpha particles ionise air to allow current
- smoke blocks the alpha particles - current drops - alarm sounds