atomic structure Flashcards

1
Q

nucleus has an overall charge that is

A

positive

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2
Q

charge on electrons

A

negative

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3
Q

subatomic particals are:

A

the partacles an element is made up of

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4
Q

relative charge of and mass of proton

A

+1 1

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5
Q

relative charge of and mass of neutron

A

0 1

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6
Q

electron

A

-1 1/1836

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7
Q

atomic number

A

number of protons

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8
Q

mass number

A

total number of protons and neutrons in the nucleus

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9
Q

isotopes have ____ chemical properties but _______ physical properties

A

isotopes have similar chemical properties but different physical properties

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10
Q

why isotopes of the same element have the same chemical properties

A

same number of electrons in outer shell

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11
Q

why differentr physical properties

A

different number of neutrons adds mass which changes these eg. lighter gas molecules collect closer to the centre

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12
Q

symbol for an isotope

A

chemical word foolowed by dash then mass number eg. carbon - 12

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13
Q

relative isotopic mass =

A

mass of an isotope relative to the mass of 1/12 th of an a tom of carbon - 12

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14
Q

relative atomic mass =

A

weighted average mass of an atom relative to 1/12 of the mass of an atom of carbon - 12

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15
Q

Relative formular mass =

A

total mass of a substance

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16
Q

relative atomic mass calculation

A

relative abundance(isotope1) x mass(isotope1) + (relative abundance (isotope2) x mass (isotope2)
/100

17
Q

predicting mass spectra

A

example chlorine :
exists as cl - 35 and cl - 37

therefore has 2 molecular ion peaks
ratio of peak heights is 3:1 as cl - 35 is 3x more abundant

will also have 3 other peaks -

35 + 35 = 70
37+37 = 74
35+37 = 74

ratio of peaks is 9:6:1

this is deduced by using the probability of each chlorine atom.

eg. 3/4 x 3/4 = 9/16
1/4 x 1/4 = 1/16
3/4 x 1/4 = 3/16 - yet this doubles as there is two of 35 = 37 when done in a grid

18
Q

what happens in mass specxtrometer

A

vaporised molecules are bombarded with a beam of high speed electrons

19
Q

knock off electrons form

A

molecular ions

molecule ——> molecule + electron

during electron bombardment

20
Q

peak with highes mass/charge (M+) =

A

molecular ion peak which gives info about the molecular mass of a compound

21
Q

M+1 peak =

A

smaller peak due to the abundance of isotopes with one extra mass

height of this peak depends on how many of the atom are present in that molecule

the more atoms the larger the peak.