atomic structure Flashcards
nucleus has an overall charge that is
positive
charge on electrons
negative
subatomic particals are:
the partacles an element is made up of
relative charge of and mass of proton
+1 1
relative charge of and mass of neutron
0 1
electron
-1 1/1836
atomic number
number of protons
mass number
total number of protons and neutrons in the nucleus
isotopes have ____ chemical properties but _______ physical properties
isotopes have similar chemical properties but different physical properties
why isotopes of the same element have the same chemical properties
same number of electrons in outer shell
why differentr physical properties
different number of neutrons adds mass which changes these eg. lighter gas molecules collect closer to the centre
symbol for an isotope
chemical word foolowed by dash then mass number eg. carbon - 12
relative isotopic mass =
mass of an isotope relative to the mass of 1/12 th of an a tom of carbon - 12
relative atomic mass =
weighted average mass of an atom relative to 1/12 of the mass of an atom of carbon - 12
Relative formular mass =
total mass of a substance
relative atomic mass calculation
relative abundance(isotope1) x mass(isotope1) + (relative abundance (isotope2) x mass (isotope2)
/100
predicting mass spectra
example chlorine :
exists as cl - 35 and cl - 37
therefore has 2 molecular ion peaks
ratio of peak heights is 3:1 as cl - 35 is 3x more abundant
will also have 3 other peaks -
35 + 35 = 70
37+37 = 74
35+37 = 74
ratio of peaks is 9:6:1
this is deduced by using the probability of each chlorine atom.
eg. 3/4 x 3/4 = 9/16
1/4 x 1/4 = 1/16
3/4 x 1/4 = 3/16 - yet this doubles as there is two of 35 = 37 when done in a grid
what happens in mass specxtrometer
vaporised molecules are bombarded with a beam of high speed electrons
knock off electrons form
molecular ions
molecule ——> molecule + electron
during electron bombardment
peak with highes mass/charge (M+) =
molecular ion peak which gives info about the molecular mass of a compound
M+1 peak =
smaller peak due to the abundance of isotopes with one extra mass
height of this peak depends on how many of the atom are present in that molecule
the more atoms the larger the peak.