Atomic Structure Flashcards

1
Q

What is an element?

A

A substance made up of only one type of atom

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2
Q

What is a mixture?

A

A compound made up of two or more elements that are not chemically linked

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3
Q

What is a compound

A

A substance made up of two or more chemical elements that are chemically combined

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4
Q

What are atoms

A

The smallest part of a substance that cannot be broken down chemically

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5
Q

What are molecules

A

Two or more atoms connected by chemical bonds

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6
Q

Atomic number

A

(Z)
The number of protons in the nucleus of an atom of an element

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7
Q

Mass number

A

(A)
Total number of protons and neutrons in the nucleus (nucleon number)

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8
Q

Explain binding energy (BE)

A

The further the electron is from the nucleus, the less the BE
Outer electrons = weaker attractive forces
Inner electrons= stronger attractive forces
To overcome the forces of attraction of the nucleus and remove and electron

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9
Q

Electron shells

A

K - 2
L - 8
M - 18

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10
Q

What is valency

A

The ability of one atom to join another

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11
Q

Ionic bonds

A

The transfer of electrons from one atom to another forming charged ion

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12
Q

Covalent bonds

A

Sharing of electrons between atoms

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13
Q

Pauli exclusion principle

A

No two electrons can be at the same state at the same time within the same matter

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14
Q

What is a nuclide?

A

A particular variety of atom characterised by a given atomic number and a given mass (an element has a fixed Z and A)

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15
Q

Isotopes

A

All the atoms of one element must have the same atomic number, but have different mass numbers
They combine with chemicals in the same way

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16
Q

Radioisotopes

A

Have an unstable nucleus due to the forces of attraction from the neutrons are not enough to bind the nucleus together and outweigh repulsive forces (protons.
The nuclide may breakup or eject radiation energy
Radioactive

17
Q

Excitation

A

When an electron moves to a higher energy level and falls back quickly
Emission of electromagnetic radiation

18
Q

Ionisation

A

When an electron is ejected from an atom, another electron from a higher energy band falls down to replace the lost electron
Emission of electromagnetic radiation

19
Q

Explain the band theory

A

When two or more atoms are in close proximity, their energy levels become modified because their electrons are influenced by the electric fields of both atoms
If many atoms are closely spaced, energy bands are produced

20
Q

What are the three energy band categories?

A

Filled bands
Valence Bands
Conduction Bands

21
Q

What are forbidden gaps?

A

Separate energy bands
Contain no permitted electrons

22
Q

Filled band

A

Energy band bellow valence band
Possess a full complement of electrons

23
Q

Valence band

A

Highest energy band with electrons tied to a particular atom
Corresponds to the valence of a single isolated atom

24
Q

Conduction band

A

Energy band above valence band
Has free electrons

25
Q

Luminescence

A

Light emission
1-Fluorescence
2-Phosphorescence
3-Thermoluminescence

26
Q

Electron traps

A

In the forbidden gap, there are imperfections in the crystal structure to create extra energy levels
An electron that settles in the electron traps can only escape from it if it can gain sufficient energy to enable it to jump upwards into the conduction band (heated)

27
Q

Fluorescence

A

The instant re-emission of the absorbed energy
The energy of light emitted depends on the difference in the energy across the luminescence centre

28
Q

Luminescence centre

A

Return the electron to a ground state from an excited state

29
Q

Phosphorescence

A

The delayed re-emission of the absorbed energy, the emission of light continues for a while after initial stimulation of the phosphor has ceased

30
Q

Thermoluminescence

A

Prompted by the introduction of heat to phosphor to excite the electron following the material’s earlier absorption of energy from radiation
Electron trap is closer to valence band
Requires more energy