atomic structure Flashcards

1
Q

Atoms

A

An atom is the smallest indivisible particle of an element that can take part in a chemical reaction.

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2
Q

Protons (charge, relative mass)

A

Charge: 1+
Relative mass: 1

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3
Q

Neutron (charge, relative mass)

A

Charge: 0
Relative mass: 1

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4
Q

Electron (charge, relative mass)

A

Charge: 1-
Relative mass: 1/1840

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5
Q

Behavior of particles in an electric field

A

Protons: deflected towards the negative plate
Electrons: deflected towards the positive plate
Neutrons: not deflected at all

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6
Q

Extent of deflection of protons and electrons

A

The extent of deflection of electrons towards the positive plate in the electric field will be greater than protons as an electron has a much smaller mass than a proton.

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7
Q

Extent of deflection equation

A

Charge / mass

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8
Q

Isotopes (definition)

A

Isotopes are atoms of the same element with different number of neutrons

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9
Q

Isotopes (properties)

A

Isotopes of the same element have the same chemical properties, because they have the same number of electrons. However, they have slightly different physical properties, due to the different relative masses of isotopes.

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10
Q

Atomic orbitals

A

An orbital is a region of space around the nucleus with the highest probability of locating the electrons

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11
Q

s orbitals

A

All s orbitals are spherical in shape, they only differ in size

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12
Q

p orbitals

A

There are 3 types of p orbitals (px,py,pz) with different orientations in space. Each p orbital has a dumb-bell shape

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13
Q

Four types of orbitals

A

s, p, d, f

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14
Q

Maximum number of electrons that can occupy each shell

A

2n 2

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15
Q

Maximum number of electrons each orbital can hold

A

2

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16
Q

Subshell s

A

1 orbital, maximum of 2 electrons

17
Q

Subshell p

A

3 orbitals, maximum 6 electrons

18
Q

Subshell d

A

5 orbitals, maximum 10 electrons

19
Q

Subshell f

A

7 orbitals, maximum 14 electrons

20
Q

Electron shell 1

A

1 subshell (1s), maximum 2 electrons

21
Q

Electron shell 2

A

2 subshell (2s, 2p), maximum 8 electrons

22
Q

Electron shell 3

A

3 subshell (3s, 3p, 3d), maximum 18 electrons

23
Q

Electron shell 4

A

4 subshell (4s, 4p, 4d, 4f), maximum 32 electrons

24
Q

4s vs 3d subshells

A

The orbitals are always filled in the order of increasing energy. Electrons always go into an empty orbital with the lowest energy first.
4s has a lower energy level than 3d. Thus, when adding electrons, the 4s orbital is filled up before the 3d orbital.

25
Q

Ions (definition)

A

An ion is formed when an atom loses or gains electron(s), such that it acquires an electrical charge. Atoms lost or gain electrons to obtain the duplet or octet configuration in order to achieve greater stability

26
Q

Formation of ions (anion)

A

When atoms gain elections, negative ions are formed (anions).
Electrons are first added into available orbitals with the lowest energy.

27
Q

Formation of ions (cations)

A

When atoms lose electrons, positive ions are formed (cations).
Electrons are first removed from orbitals with the highest energy. When the 3d orbital is filled, the energy level of the 4s orbital will increase above that of the 3d orbital. Thus, during the formation of cations, the electrons will be removed from the 4s orbital before the 3d orbital.

28
Q

Isoelectric species

A

Any atom or ions with same number of electrons are said to be isoelectronic.