Atomic Structure Flashcards

1
Q

Define binding energy.

A

The energy involved in the formation of a nucleus from free protons and neutrons.

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2
Q

Define principal quantum number.

A

The number of subshells in each shell.

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3
Q

Define ground state.

A

When the electrons are in orbitals of lowest available energy level.

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4
Q

Define excited state.

A

When at least 1 electron absorbs energy and is promoted to a higher energy level.

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5
Q

State the Aufbau Principle.

A

Electrons always go into an empty orbital with the lowest energy available.

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6
Q

State Hund’s Rule.

A

Where a number of orbitals of equal energy are available, electrons occupy them singly first before any pairing occurs.

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7
Q

State the Pauli Exclusion Principle.

A

Each orbital can only hold 2 electrons of opposite spin.

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8
Q

Define atomic number.

A

Number of protons contained in nucleus is same as number of electrons surrounding the nucleus. No 2 elements can have the same atomic number.

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9
Q

Define mass number.

A

Total number of protons and neutrons in nucleus.

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10
Q

Define nucleons.

A

A constituent (neutron or proton) of an atomic nucleus.

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11
Q

Define isotopes.

A

Atoms with the same number of protons but different number of neutrons. Elements with same chemical properties, but different physical properties, such as melting point, density, radioactivity…

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12
Q

Define orbital.

A

The region of space where there is a high probability of locating electrons.

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13
Q

Define shell.

A

A group of orbitals with the same principal quantum number n.

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14
Q

Define subshell.

A

A group of orbitals in the same shell and of the same energy level.

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15
Q

Define period.

A

Each horizontal row of elements in the periodic table.

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16
Q

Define group.

A

Each vertical column of elements in the periodic table.

17
Q

Define ionisation energy.

A

The energy required to remove 1 mole of electrons from 1 mole of gaseous atoms.

18
Q

Define electronvolt.

A

A unit of energy acquired by an electron when it has accelerated through a potential difference of 1 volt.

19
Q

Define excitation energy.

A

The energy required to raise an atom from its ground state to an excited state.

20
Q

State Heisenberg’s Uncertainty Principle.

A

A principle that states that it is physically impossible to measure simultaneously the exact position and exact momentum of a particle.

21
Q

What is wave-particle duality ?

A

A theory that proposes that every elementary particle has wave and particle properties.

22
Q

Define relative atomic mass.

A

Weighted mean mass of masses of all isotopes of an element relative to the mass of 1/12 of carbon-12 atom.

23
Q

Define convergence limit.

A

The point where the energy levels get closer together.

24
Q

What is the screening effect?

A

It arises from the mutual repulsion between inner shell electrons and outer shell electrons.

25
Q

Define energy levels.

A

Electrons in atoms can only have certain energy values.

26
Q

What is an emission spectrum?

A

Coloured lines on a black background.

27
Q

What is an absorption spectrum?

A

Black lines on a coloured background.

28
Q

What is the Lyman series?

A

Electrons falling to lowest energy level (n=1). It is in the UV region.

29
Q

What is the Bahmer series?

A

Electrons falling to the second lowest energy level (n=2). It is in the visible region.

30
Q

What is the Paschen series?

A

Electrons falling to the third lowest energy level (n=3). It is in the infrared region.