Atomic Structure Flashcards

1
Q

Maximum number of electrons in a shell equation

A

2n^2 E.g second 2^2=4 x2 = 8

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2
Q

Atomic orbital

A

Region around the nucleus that can hold up two electrons with opposite spins

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3
Q

Shape of s orbital and number it can hold

A

Sphere and 2

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4
Q

Shape of p orbital

A

Infinity shape and 6 electrons

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5
Q

Subshell

A

Is all of the orbitals of the same type in same shell

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6
Q

Trend in energy with sub shell

A

Higher the shell higher the energy

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7
Q

First ionisation energy

A

The energy needed to remove one mole of electrons from one mole of atoms in the their gaseous state to form one mole of 1+ ions

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8
Q

Second ionisation energy

A

Energy to remove one mole of electrons from one like of 1+ ions in their gaseous state to form one mole of 2+ ions

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9
Q

Three factors that affect ionisation energy

A

Atomic radius
Shielding
Nuclear charge

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10
Q

Atomic radius

A

Distance between nucleus and outer electrons as atomic radius increase increases force of attraction between nucleus and outer electron decreases

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11
Q

Nuclear charge

A

The greater number of protons greater the force of attraction between the outer electrons and nucleus

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12
Q

Shielding

A

Electrons in outer shell are repelled by electrons in inner shell

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13
Q

First ionisation energy down a group

A

Decreases as we go down a group as atomic radius increases so outer electron shell is further away from nucleus more shielding also occurs.

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14
Q

Ionisation energy across a period

A

Ionisation energy increases across a period due to similar shielding but greater nuclear charge

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15
Q

Isotopes

A

Atoms of the Same element with different number of neutrons and different masses

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16
Q

Why do isotope react same way

A

They have same electron configuration/ outer electron

17
Q

Mass spectrometer

A
  1. Place sample into sample chamber this sample contains all diff isotopes of that element
    2.ionisation occurs which converts all atoms into positive ions so they are attracted to negatively charged playe
    3.Negative charge plate causes ions to accelerate and increases kinetic energy so that all ions with same charge will have same kinetic energy
  2. They then drift down chamber to the detector at different velocities
  3. Lighter ions move faster than heavier and once ur reaches detector it gains electrons from the detector
  4. The time taken to reach detector is used by machine to determine mass
  5. Size of the current produced when each isotope hits detector is used to determine the abundance