Atomic Structure Flashcards
Maximum number of electrons in a shell equation
2n^2 E.g second 2^2=4 x2 = 8
Atomic orbital
Region around the nucleus that can hold up two electrons with opposite spins
Shape of s orbital and number it can hold
Sphere and 2
Shape of p orbital
Infinity shape and 6 electrons
Subshell
Is all of the orbitals of the same type in same shell
Trend in energy with sub shell
Higher the shell higher the energy
First ionisation energy
The energy needed to remove one mole of electrons from one mole of atoms in the their gaseous state to form one mole of 1+ ions
Second ionisation energy
Energy to remove one mole of electrons from one like of 1+ ions in their gaseous state to form one mole of 2+ ions
Three factors that affect ionisation energy
Atomic radius
Shielding
Nuclear charge
Atomic radius
Distance between nucleus and outer electrons as atomic radius increase increases force of attraction between nucleus and outer electron decreases
Nuclear charge
The greater number of protons greater the force of attraction between the outer electrons and nucleus
Shielding
Electrons in outer shell are repelled by electrons in inner shell
First ionisation energy down a group
Decreases as we go down a group as atomic radius increases so outer electron shell is further away from nucleus more shielding also occurs.
Ionisation energy across a period
Ionisation energy increases across a period due to similar shielding but greater nuclear charge
Isotopes
Atoms of the Same element with different number of neutrons and different masses
Why do isotope react same way
They have same electron configuration/ outer electron
Mass spectrometer
- Place sample into sample chamber this sample contains all diff isotopes of that element
2.ionisation occurs which converts all atoms into positive ions so they are attracted to negatively charged playe
3.Negative charge plate causes ions to accelerate and increases kinetic energy so that all ions with same charge will have same kinetic energy - They then drift down chamber to the detector at different velocities
- Lighter ions move faster than heavier and once ur reaches detector it gains electrons from the detector
- The time taken to reach detector is used by machine to determine mass
- Size of the current produced when each isotope hits detector is used to determine the abundance