ATOMIC STRUCTURE Flashcards

1
Q

Reative mass and charge of proton

A

1, 1+

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2
Q

Relative mass and charge of neutron

A

1, 0

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3
Q

Relative mass and charge of electron

A

1/1836,1-

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4
Q

Behaviour of protons in an electric field

A

Deflects towards the negative plate

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5
Q

Behaviour of neutrons in an electric field

A

N/A

Because they dont have a charge

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6
Q

Behaviour of electrons in an electric field

A

Deflects towards the positive plate

Greater deflection than protons because electrons have a smaller mass

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7
Q

Where is most of an atoms mass concentrated at?

A

Nucleus

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8
Q

Define isotopes

A

Atoms of the same element with same number of electrons and protons but a different neutron number

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9
Q

Define orbital

A

A region holding upto two electrons w/ opposite spin

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10
Q

Describe the shape of an s and a p orbital

A

s-orbital: spherical
p-orbital: dumb-bell

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11
Q

Define a subshell

A

Division of electron shells into different orbitals

Subshells- s,p,d,f

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12
Q

How electrons fill up orbitals?

A

They fill up the lowest energy orbital available

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13
Q

How many orbitals and electrons are present in s, d, & f subshell?

A
  • s: 1 orbital, 2 electrons
  • p: 3 orbitals, 6 electrons
  • d: 5 orbitals, 10 electons
  • f: 7 orbitals, 14 electrons
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14
Q

which shubshell orbital has the lowest and highest energy levels?

A

s has the lowest energy level whilst
d has the highest energy level

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15
Q

What subshells are found in shells 1-4?
What is the max no. of electrons that can be found in each shell?

A

1-s-2
2-s,p-8
3-s,p,d-18
4-s,p,d,f-32

shell-subshell-no. of electrons present

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16
Q

what is principal quantum number (n)?

A

n= the shell that the electron occupies
greater the “n” is the higher the energy is, and farther the shell is from the nucleus.

17
Q

Define first ionisation energy

A

The energy required to remove an electron from each atom in one mole of gaseous atoms to form one mole of gaseous 1+ ions.

18
Q

Is first ionsation of energy exo or endo thermic?

A

Endothermic

19
Q

Trend in first ionisation energy across period 2 & 3?

A

As you go along the period, first ionisation energy increases.

20
Q

why does first ionisation energy increase across a period?

A
  • Nuclear charge increases
  • Atomic radius decreases
  • Shielding remains the same
  • Hence electrostatic attraction increases, so more energy is required to overcome these forces to remove an electron from an atom, Ionisation energy therefore increases
21
Q

Trend in first ionisation energy down the group

A

Ionization energy decreases down the group

22
Q

Why does the first ionisation energy decrease down a group?

A

nuclear charge increases but-
* atomic radius increases
* shielding increases
* electrostatic attraction decreases, so less energy is needed to overcome these forces to remove an electron from the atom.

atomic radius and shieliding outweigh the nuclear charge

23
Q

Which two elements have an exception and do not follow the electronic configuration pattern?

A

Chromium
Copper with +2

24
Q

Explain the decrease between beriliyium and boron

across period

A

Fifth electron of boron is in the 2p subshell, which is further away from the nucleus than the 2s subshell of beryllium

25
Q

Explain the decrease between nitrogen, oxygen and phosphurus

A

This is due to spin pair repulsion in the 2p orbital of oxygen.