Atomic Structure (1) Flashcards
Lyman series
energy level n greater than or equal to 2 to n= 1.
Larger energy transition, it has shorter photon wavelengths.
Balmar series
Energy level n greater than or equal to 3 to n = 2.
Paschen series
Energy level n greater than or equal to 4 to n = 3.
Heisenberg uncertainty principle
it is impossible to determine with perfect accuracy the momentum and position of electrons. We can do describe the probability of electrons with a given region of space.
Pauli exclusion principle
No two electrons in a given atom can possess the same set of four quantum numbers.
Principle quantum number
denoted by letter (n).
Difference in energy between the shell decreases as the distance from the nucleus increases because the energy difference [1/n^2 initial - 1/n^2 final]
Maximum number of electrons within a subshell
4(l) +2
4 times angular momentum + 2
Aufbau’s principle
electrons fill from lower to higher energy subshells
Hund’s rule
within a given subshell, orbitials are filled such that there are a maximum number of half filled orbitials with parallel spins.
azimuthal quantum number (angular momentum)
(l) describes the subshells within a principle energy level
(s, p ,d,f )
l = n- 1
magnetic quantum number
specifies the particular orbital subshell where an electron is likely to be found at a given moment in time.
Spin quantum number
indicates spin orientation (+/- 1/2)
Paramagnetic
materials have unpaired electrons that align with magnetic fields, attracting the material to a magnet.
Diamagnetic
materials have all paired electrons, which cannot easily be realigned; they are replled by magnets.
Absorption vs. Emission
Absorption: When electron moves from LOWER to HIGHER state, they must absorb energy in form of a light.
Emission: When electrons move from HIGHER to LOWER state, they must emmit the energy in form of light.