Atomic Structure (1) Flashcards

1
Q

Lyman series

A

energy level n greater than or equal to 2 to n= 1.

Larger energy transition, it has shorter photon wavelengths.

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2
Q

Balmar series

A

Energy level n greater than or equal to 3 to n = 2.

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3
Q

Paschen series

A

Energy level n greater than or equal to 4 to n = 3.

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4
Q

Heisenberg uncertainty principle

A

it is impossible to determine with perfect accuracy the momentum and position of electrons. We can do describe the probability of electrons with a given region of space.

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5
Q

Pauli exclusion principle

A

No two electrons in a given atom can possess the same set of four quantum numbers.

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6
Q

Principle quantum number

A

denoted by letter (n).

Difference in energy between the shell decreases as the distance from the nucleus increases because the energy difference [1/n^2 initial - 1/n^2 final]

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7
Q

Maximum number of electrons within a subshell

A

4(l) +2

4 times angular momentum + 2

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8
Q

Aufbau’s principle

A

electrons fill from lower to higher energy subshells

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9
Q

Hund’s rule

A

within a given subshell, orbitials are filled such that there are a maximum number of half filled orbitials with parallel spins.

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10
Q

azimuthal quantum number (angular momentum)

A

(l) describes the subshells within a principle energy level

(s, p ,d,f )

l = n- 1

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11
Q

magnetic quantum number

A

specifies the particular orbital subshell where an electron is likely to be found at a given moment in time.

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12
Q

Spin quantum number

A

indicates spin orientation (+/- 1/2)

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13
Q

Paramagnetic

A

materials have unpaired electrons that align with magnetic fields, attracting the material to a magnet.

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14
Q

Diamagnetic

A

materials have all paired electrons, which cannot easily be realigned; they are replled by magnets.

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15
Q

Absorption vs. Emission

A

Absorption: When electron moves from LOWER to HIGHER state, they must absorb energy in form of a light.

Emission: When electrons move from HIGHER to LOWER state, they must emmit the energy in form of light.

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16
Q

Isotope

A

same atomic number, but different mass

17
Q

Avagadro number

A

6.02 x 10^ 23

18
Q

Electron from lower to higher state

AHED

A
Mnemonic: AHED
A: absorb light
H: higher potential
E: excited
D: distant from the nucleus
19
Q

Energy formula

A
E = hf
E= hc/ λ
c = f x λ
h = planck constant (6.626 x 10^ -34)
20
Q

Rydberg unit of energy (Rh)

A

Rh = 2.18 x 10^ -18

21
Q

Energy formula for initial minus final

A

E = -Rh [1/n^2 (initial) - 1/n^2 (final)]

Rh = 2.18 x 10^-18

22
Q

maximum number of electron allowed in a single atomic energy level in terms of n

A

2n^2