Atomic and Nuclear Structure Flashcards
A = Atomic …
Atomic Mass Number
Total number of protons + neutrons.
Z = Atomic …
Atomic Number. Total number of protons.
Determines the number of electrons, and therefore the chemical properties of the atom.
A - Z = …
A - Z = atomic mass number - number of protons = number of neutrons.
Isotopes have …
Same number of protons, different number of neutrons.
Same chemical behavior, different mass, and different nuclear decay properties.
Energy-mass relation?
Energy–momentum relation?
E = mc^2
E^2 = (pc)^2 + (m_0c^2)^2
Electron mass?
How many times the proton mass?
0.511 MeV
roughly 1/1800 of proton or neutron mass
Proton mass?
More or less than neutron mass?
How many times the electron mass?
938.3 MeV
A bit less than neutron mass.
roughly 1836 times electron mass
Neutron mass?
More or less than proton mass?
939.6 MeV
A bit more than proton mass
Electron Orbits - Principle quantum
Letters, and number of electrons.
Letters: K, L, M, N, O, …
Principle Quantum number: 1, 2, 3, 4, 5, …
Number of electrons 2n^2
n = quantum number
Electron binding energy vs. proximity to nucleus?
Electron binding energy increases with proximity to the nucleus by radius squared (r^2).
Closer to nucleus means lower energy level (more favorable).
Change in electron orbit results in / is caused by?
Release and absorption of energy.
Absorbed energy pushes electron in higher orbit (excitation) or frees it from atom if the absorbed energy is larger than its binding energy (ionization).
Falling down from higher to lower orbits releases energy equal to the energy difference of the two shells.
Energy is either transferred to higher shell electrons, which will be ejected from the atom as an Auger electron.
or
emitted in the form of a characteristic x-ray (photon)
What defines the chemical properties of an atom?
Number of protons (Z).
Same number of protons but different number of neutrons are the isotopes of an atom.
The four fundamental forces in nature?
Strong Nuclear Force - “glues” the nucleus together - 1
Electromagnetic (Coulombic) Force - attraction and repulsion of charged particles - 1/37
Weak Nuclear Force - inside particles - 10^-6
Gravity - 10^-39
Which fundamental forces are infinite, which are short ranged?
Infinite: Gravity and EM (1/r^2 dependence)
Short ranged (few femtometers): Strong and weak forces.
Size of hydrogen nucleus and electron cloud.
Nucleus: 1.70 fm (Femtometer = 1 × 10^-15 m)
Electron cloud: ~ 0.1 nm = 1 × 10^-10 m = 1 Å