Atmospheric Thermal Structure Flashcards
What layer of the atmosphere contains 80% of the total mass of the atmosphere and almost the whole quantity of water vapor?
Troposphere
What determines how a pollutant can disperse through the atmosphere?
Rate of change of temperature with altitude.
What are the physical properties of the atmosphere (state variables)?
Pressure, Density, and temperature.
How is the atmosphere divided into layers?
By the vertical distribution of temperature.
T/F: In the troposphere, temperature decreases with height?
True
Lapse Rate
Γ = -dT/dz
What are the features of the boundary layer?
- Surface Layer
- Convective mixed layer
- Temperature Inversion Layer
- Residual Layer
What does the boundary layer depend on?
Ground temperature
How is a surface inversion created during the night?
The ground cools radiatively, causing air temperatures to increase with increasing height from the ground.
T/F: Pollutants are more likely to be trapped in the surface layer at day?
False, because the surface inversion causes pollutants to stay trapped.
Ideal gas law specifically for dry air?
p = ρd Rd T
- ρ is rho, density
Rd = R*/ Md, gas constant
T = temperature
Ideal gas law for moist air?
p = ρv Rd Tv
- ρ is rho, density
Rv = R*/Mw
Tv = virtual temperature
What is virtual temperature tv?
The temperature a
hypothetical sample of dry air would need to have in order to have the same density as the sample of moist air at the same pressure.
What is the virtual temperature formula?
Tv = [1 + 0.61*rv ] * T
Hydrostatic Equations
F pressure = F gravity
−δp = gρδz
At the limit of δz -> 0
∂p/ ∂z = -g*ρ
Hydrostatic balance with ideal gas law:
∂p/ ∂z = - p*g/ Rd * Tv
1st law of thermodynamics
With Specific heat capacity
dq = cvdT +pdα
dq = cpdT − αdp
cp = cv + R
Where is cv = 717 JK-1kg-1 and cp = 717 J K-1kg*-1 are the
specific heat at constant volume and pressure respectively.
Isobaric
Constant pressure
dp = 0
δq = cp*dT
Isothermal
Constant temperature
dT = 0
du = 0 since dT = 0
-> δq = δw
All heat goes into work.
Isochoric
Constant volume
dV = 0
δw = 0 since dV = 0 (and dα = 0)
δq = du = cv*dT
No work, all heat into T changes.
Adiabatic
No heat exchanged,
δq = 0, du = - δw since δq = 0
How does temperature change with height for a rising thermal?
Temperature is the highest when nearer to the ground