Atmospheric Emissions Flashcards

1
Q

Major Environmental Concerns

A
  • Atmospheric Emissions
  • Water Pollution
  • Solid and Hazardous Wastes
  • Radioactive Wastes
  • Depletion of Natural Resources
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2
Q

Six major air pollutants

A
  • Particulate matter (PM)
  • Sulfur dioxide, SO2
  • Carbon monoxide, CO
  • Nitrogen dioxide, NO2
  • Ground-level ozone, O3
  • Lead, Pb

These air pollutants are known as criteria air pollutants

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3
Q

Primary Standards VS Secondary Standards VS What are they specified on?

A

Primary Standards:
They are designed to protect human health

Secondary Standards:
They are related to human welfare
Standards are specified on:

  1. An hourly or daily basis (acute health effects)
  2. An annual average basis (chronic health effects)
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4
Q

Particulate Matter (PM)

A

It is a mixture of small solids or liquid particles suspended in air (TSP)
Examples:
dust
smoke
haze
ash

Respiratory problems

What is producing PM?
Fuel combustion
Industrial and manufacturing processes

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5
Q

PM 10

A

PM 10:
Particles smaller than 10 microns (or 10 micrometers)
They penetrate deeply into the lungs and they release pollutants
on lung surfaces

PM 2.5 follows same logic = Nitrate Particles

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6
Q

Sulfur Dioxide (SO2)

A

Who is producing SO2:

Combustion of coal and oil
Metal smelting
Other industrial processes
Power plants

Respiratory Problems

Some plants and crops are also sensitive to SO2 and may be damaged
SO2 can cause acid rain

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7
Q

Carbon Monoxide (CO)

A

Who is producing CO:

Combustion of fossil fuel or other carbon
containing materials which are not completed
combusted

Automobiles are the dominant source of CO

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8
Q

Nitrogen Dioxide (NO2)

A

Who is producing NO2:
Fuel combustion

NO 2 is in the family of nitrogen oxides (NOx)

NO x react chemically in the atmosphere and produce nitrate particles,
PM 2.5

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9
Q

Ozone (O3)

A

There are two type of O3 :
Ozone in the stratosphere (good ozone)
Ozone in ground-level (bad ozone)

Ground-level ozone:
It is formed by complex chemical reactions in the atmosphere involving nitrogen oxides (NOx)
and hydrocarbon gases (volatile organic compounds, VOC, or reactive organic gases, ROG)

                           summer sunlight NO x + VOC(ROG) ------------------> O3 + Other
                             atmosphere Other Effects: Deteriorates paints and fabrics  Rubber products become brittle and cracked Interferes with the ability of plants to produce and store food Ozone damage to plants and trees causes half a billion dollars per year od agricultural crops loss in U.S. alone
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10
Q

How to reduce O3

A

How to reduce ground-level ozone?
1. Reduce NO x
2. Reduce hydrocarbon emissions

Sources of Hydrocarbon Emissions:
Transportation sector
Petroleum refineries
Chemical manufacturing plants
Gasoline distribution and storage facilities
Dry cleaners

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11
Q

Lead (Pb)

A

Who is producing Pb:
Automobiles using leaded gasoline
Lead smelting and manufacturing processes

Health Problems:
Neurological damage
Adverse effects on organs (liver and kidneys)

Domestic sources of Pb:
Lead erosion from water pipes
Lead paint in buildings

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12
Q

Air Toxics

A

In addition to air pollutants there are also substances called
hazardous air pollutants (HAPs) or air toxics

Air Toxics:
Are chemicals emitted in much more smaller quantities
than criteria air pollutants, but their effects are severe
Examples:
Asbestos
Benzene

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13
Q

Acid Deposition, Acid Rain

A

Acid Rain:
The fallout of acidic particles or any type of precipitatio
(rain, fog, mist, or snow)
Ph is about 5.6

Main Source of acidity:
Emissions of sulfur dioxide (SO2) from power
plants hundreds of miles away

Sulfur dioxide sulfate particles ————–> other acidic species
NOx emissions ————-> acid loadings

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14
Q

Effects of Acid Rain:

A

Acidification of lakes and streams
Acidified waters can kill fishes, other aquatic organisms
or prevent them from reproduction
Decline of some species of trees
Soil acidification
Soil erosion
Deterioration of some building materials and monuments
made of limestone or marble

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15
Q

How to reduce Acid Rain

A

Reduce sulfur dioxide (SO2) emissions

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16
Q

What causes O3 depletion

A

Ozone is being depleted by a family of
chemicals known as CFCs
CFCs = chlorofluorocarbons

17
Q

Stratospheric Ozone Depletion
How CFCs destroy O3:

A
  1. CFCs enter in the atmosphere as a gaseous emission
    or evaporation from liquids
  2. CFCs remain in the air and eventually reach the stratosphere
  3. The intense UV radiation in the O3 layer breaks apart
    and releases free chlorine atoms
  4. Each chlorine atom reacts chemically and destroy
    large number of O3 molecules
18
Q

Greenhouse Gases

A

Greenhouse Gases

  1. Carbon dioxide, CO2
  2. Methane, CH4
  3. Nitrous oxide, N2O
  4. Halocarbons

They are called greenhouse gases because they trap heat in the
atmosphere the same way that glass helps to trap solar energy
in a greenhouse

  1. Solar energy is radiated from the sun at short wave-lengths
    (ultraviolet radiation) and is partially absorbed by the earth’s surface
  2. The earth’s surface radiates energy back to space, but at much
    longer wave-lengths (infrared radiation)
  3. The balance between incoming and outgoing radiation determines
    the temperature of the planet
  4. CO 2 and vapor H2O absorb outgoing energy. Because less energy
    now escapes to outer space, these gases produce a natural
    warming effect
19
Q

Greenhouse gases vs Air Pollutants

A

Greenhouse Gases:
They have long lifetime in the atmosphere
(decades to centuries)
They are stable, nonreactive
Increase of CO2 cannot be easily reversed

Air Pollutants:
They are chemically reactive
They can wash out of the atmosphere in a matter
of days

20
Q
A