AS Organic definitions Flashcards
Hydrocarbon
A compound of hydrogen and carbon only
Homologous series
A series of organic compounds having the same functional group but with each successive member differing by CH2
Functional group
A group of atoms responsible for the characteristic reactions of a compound
Saturated
Containing single bonds only
Unsaturated
Containing at least one carbon-carbon multiple bond
Empirical formula
The simplest whole number ratio of atoms of each element present in a compound
Molecular formula
The actual number of atoms of each element present in a molecule
Structural isomers
Compounds with the same molecular formula but with different structural formulae
Stereoisomers
compounds with the same structural formula but with different arrangements of atoms in space
E/Z isomerism
an example of stereoisomerism, in terms of restricted rotation about a carbon-carbon double bond and the requirement for two different groups to be attached to each carbon of the C=C group
Cis-trans isomerism
A special case of E/Z isomerism in which two of the substituent groups are the same
Fractional distillation
Separation of a liquid mixture into fractions with different boiling points
Catalytic cracking
The breaking down of long chained saturated hydrocarbons to form more useful alkanes (shorter chained) and alkenes
Biofuel
A fuel that is derived from recently living material such as plants o from the waste of animals
‘Curly arrow’
The movement of an electron pair, showing either the breaking or formation of a covalent bond
Radical
A species with an unpaired electron
Homolytic fission
The breaking of a covalent bond where each of the bonded atoms retains one of the electrons from the bonded pair of electrons
Heterolytic fission
The breaking of a covalent bond where one of the bonded atoms retains both of the electrons from the bonded pair of electrons
Electrophile
An electron pair acceptor
Nucleophile
An electron pair donor
Catalyst
Speeds up a reaction without being consumed by the overall reaction
Volatility
The ease that a liquid turns into a gas (increases as boiling point decreases)
Reflux
The continuous boiling and condensing of a reaction mixture
Atom economy
(Molecular mass of desired product) ÷ (sum of molecular mass of all products) x100