AS Organic definitions Flashcards

1
Q

Hydrocarbon

A

A compound of hydrogen and carbon only

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2
Q

Homologous series

A

A series of organic compounds having the same functional group but with each successive member differing by CH2

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3
Q

Functional group

A

A group of atoms responsible for the characteristic reactions of a compound

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4
Q

Saturated

A

Containing single bonds only

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5
Q

Unsaturated

A

Containing at least one carbon-carbon multiple bond

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6
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element present in a compound

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7
Q

Molecular formula

A

The actual number of atoms of each element present in a molecule

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8
Q

Structural isomers

A

Compounds with the same molecular formula but with different structural formulae

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9
Q

Stereoisomers

A

compounds with the same structural formula but with different arrangements of atoms in space

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10
Q

E/Z isomerism

A

an example of stereoisomerism, in terms of restricted rotation about a carbon-carbon double bond and the requirement for two different groups to be attached to each carbon of the C=C group

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11
Q

Cis-trans isomerism

A

A special case of E/Z isomerism in which two of the substituent groups are the same

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12
Q

Fractional distillation

A

Separation of a liquid mixture into fractions with different boiling points

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13
Q

Catalytic cracking

A

The breaking down of long chained saturated hydrocarbons to form more useful alkanes (shorter chained) and alkenes

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14
Q

Biofuel

A

A fuel that is derived from recently living material such as plants o from the waste of animals

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15
Q

‘Curly arrow’

A

The movement of an electron pair, showing either the breaking or formation of a covalent bond

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16
Q

Radical

A

A species with an unpaired electron

17
Q

Homolytic fission

A

The breaking of a covalent bond where each of the bonded atoms retains one of the electrons from the bonded pair of electrons

18
Q

Heterolytic fission

A

The breaking of a covalent bond where one of the bonded atoms retains both of the electrons from the bonded pair of electrons

19
Q

Electrophile

A

An electron pair acceptor

20
Q

Nucleophile

A

An electron pair donor

21
Q

Catalyst

A

Speeds up a reaction without being consumed by the overall reaction

22
Q

Volatility

A

The ease that a liquid turns into a gas (increases as boiling point decreases)

23
Q

Reflux

A

The continuous boiling and condensing of a reaction mixture

24
Q

Atom economy

A

(Molecular mass of desired product) ÷ (sum of molecular mass of all products) x100