arrhenius equation Flashcards
what does the arrhenius equation do?
links activation energy and temperature to the rate constant
what is arrhenius equation?
k = Ae (power) -Ea / RT
what is k?
rate constant
what is A?
arrhenius constant
what is e?
exponential factor
e(power)x on calculator
what is Ea?
activation energy (J)
what is R?
gas constant (JK-1mol-1)
8.314
what is T?
temperature (K)
explain the relationship between k and Ea
as Ea decreases, k increases
- as activation energy drops, rate of reaction increases as more particles have enough energy to collide
explain the relationship between k and temperature
as temperature increases, k increases
- more particles have enough kinetic energy to collide so rate of reaction increases
summarise the steps in calculating activation energy using arrhenius
take natural log of both sides
- to remove exponential
lnK= lnA -Ea/RT
rearrange
Ea/RT = lnA - lnK
Ea = RT x (lnA-lnK)
substitute numbers into calculator