AOS1 Atomic Structure, Periodic Trends and Calculations Flashcards
The Order of subshell filling
1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p6
The Aufbau Principle
states that subshells are filled in order from lowest to highest energy, and that lower energy subshells will be COMPLETELY FILLED before electrons move into a higher-energy subshell.
Paulis Exclusion principle
States that only a maximum of two electrons may be found in any given atomic orbital and that if an orbital is filled, the electrons will have opposite spin
Hunds rule of max multiplicity
Every orbital in a subshell being singly occupied ( half filled ) BEFORE any orbital in that subshell is doubly occupied ( filled )
in addition, all have filled orbitals have the same spin
Definition of Electronegativity
Is the strength with which atoms of an element attract electrons when they are combined with other elements ( think tug of war )
Definition of Atomic Radius
Half the distance between two nuclei of a molecule, assuming they are between two identical atoms and a single covalent bond
How does the Electronegativity of elements change across a period ( L to R )
It Increases
How does the Electronegativity of elements change down a group
It decreases
How does the atomic radius of elements change across a period ( L to R )
It decreases
How does the atomic radius of elements change down a group
It increases
How does the core charge of elements change down a group
It stays constant
How does the core charge of elements change across a period ( L to R )
It Increases
what is the first ionization energy?
The First ionization energy is defined as the amount of energy required to remove an electron from each of mole of a gaseous atom.
Trends of Ionization energy down a group
As you move down a group the first ionisation energy decreases ( required less energy to extract the most valence electron )
Trends of Ionization energy across a period ( L to R )
The first ionization energy increases. (more energy requierd to remove an electron)