Analyzing organic reactions Flashcards

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1
Q

This type of acid accepts electrons in the form of a covalent bond

A

Lewis acid

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2
Q

This type of acid is a species that donates a proton

A

Bronsted-Lowry acid

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3
Q

This type of base is an electron donor (donates an electron so that it can be made into a covalent bond)

A

Lewis base

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4
Q

This type of base is a proton acceptor

A

Bronsted-Lowry base

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5
Q

____ is the acid dissociation constant

A

Ka

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6
Q

The higher the pKa, the _____ acidic something is. Similarly, the lower the pKa, the ____ acidic.

A

Less

More

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7
Q

An ______ is the indicator of the hypothetical charge an atom would carry if all its bonds were ionic

A

Oxidation state

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8
Q

If an atom is being oxidized, the number of bonds to oxygen or other heteroatoms _____

A

Increases

(Referred to as loss of electrons since more bonds are being formed)

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9
Q

If an atom is being reduced, the number of bonds to hydrogen _____

A

Increases

(Referred to as gaining electrons since H is less electronegative than basically everything)

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10
Q

Redox reactions tend to act on the functional group with ____ priority

A

Highest

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11
Q

How are protecting groups utilized during redox reactions?

A

They protect the functional group that you want to remain in tact. Ex: Adding to a carboxylic acid, then removing the protecting group after the redo reaction has taken place on the functional group you intended)

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12
Q

SN1 reactions are stereo_____ while SN2 reactions are stereo_____

A

Selective

Specific

(SN1 reactions make planar carbocations, so the new group can add to either side. SN2 reactions have LG’s and addition occurring at the same time, so it can only take the spot that is not currently occupied by the LG)

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