Amount of substance Flashcards

1
Q

What is the equation involving mass, moles and mr?

A

mass= moles X mr

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2
Q

What is the equation involving moles, conc and vol?

A

moles= conc X vol

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3
Q

What is included in the PV=nRT equation?

A

Pressure (Pa) X volume (m^3) =

no. of moles X gas constant X temperature (K)

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4
Q

How do you convert dm^3 and cm^3 into m^3 ?

A

cm^3 /1,000,000 = m^3 (divide by 1 million)

dm^3 /1,000 =m^3 (divide by 1 thousand)

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5
Q

How do you convert Kpa and Mpa and atm into Pa?

A

Kpa (X 1,000) = Pa
Mpa (X 1,000,000) = Pa
1atm = 101,000 Pa

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6
Q

For concentration, how do you get from mol d^-3 to g dm^-3 ?

A

You multiply by the mr

mass=molesXmr

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7
Q

For temperature, how do you convert degrees celsius into kelvin?

A

You add 273.

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8
Q

What does concordant mean?

A

It’s a level of accuracy and it means within +/- 0.10cm^3

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9
Q

How do you calculate atom economy?

A

mr of the desired product
/total mr of the reactants
X100 (percentage)

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10
Q

What is atom economy?

A

A measure of what proportion of the products of a reaction are the desired product and how much is waste.

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11
Q

Do you need ratio for atom economy?

A

Yes.

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12
Q

Which of percentage yield and atom economy can be changed?

A
Percentage yield  (e.g. human error)
(Atom economy stays the same.)
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13
Q

Do you need ratio for percentage yield ?

A

Sometimes.

If working out theoretical mass=for ratio of moles

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14
Q

Do you need ratio for percentage yield ?

A

Sometimes.

If working out theoretical mass=for ratio of moles.

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15
Q

How do you go from tonnes, kg, or mg to g?

A

1 ton = 1,000,000g (X1,000,000)
1kg = 1000g (X1,000)
1mg = 0.001g (/1,000)

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16
Q

Finding empirical formula and molecular formula of unknown compound

A

Mr of element/ mr of thing it’s in
X mass
/mr of element
Both/ the smallest

17
Q

Practical steps for finding x for a hydrated sample

A
  1. Weigh empty boiling tube with a balance and record in table.
  2. Place about 2cm^3 depth of your hydrated sample and record in table.
  3. Heat tube for 1min (using test tube holders).
  4. Record the mass of the tube.
  5. Repeat steps 3 and 4 until mass remains constant. (if still steam = not constant = more water to still be lost).
18
Q

How to make a standard solution?

A

1.Add solid to a small beaker & add approx. 50cm^3 of distilled water & stir until fully dissolved.
2.Transfer this into a 250cm^3 volumetric flask using a funnel (no filter=fully dissolved)
3.Rinse beaker with distilled water & add washings
4.Slowly add water until near meniscus
5.Using a dropper add water until the meniscus is level with the line (using eye-level)
6.That is 250cm^3
7.Place stopper on the top & invert 10 times to mix the solution thoroughly
conc=moles/vol(in dm^3) solid=weigh by diff moles=mass/mr

19
Q

How do you weigh by difference?

A

1.Zero the balance
2.Place the weighing boat on the balance (M1)
3.Add the rough amount of solid to the boat and record its mass (M2)
4.Add the solid mass to a beaker then record the mass of the boat again (M3)
Subtract M2-M3 = exact mass of solid in beaker.

20
Q

Steps for titration (acid added to alkali)

A
  1. Use pipette and pipette filler to add 25cm^3 of sodium hydroxide solution to a clean conical flask
  2. Add a few drops of indicator then put the conical flask on a white tile
  3. Fill the burette w/ hydrochloric acid & note starting volume
  4. Slowly add acid from burette to alkali in the conical flask, swirling to mix
  5. Stop adding acid when the end-point is reached (more accurate if added drop by drop near end-point) & note the final volume reading
  6. Calculate volume of the acid added to neutralise (titre value)
  7. Repeat 1-5 until concordant titres are obtained
21
Q

What does end-point mean?

A

When the indicator first permanently changes colour.

22
Q

Why rinse the inside of a conical flask during titration? & why doesn’t this affect the accuracy of the titre?

A

Returns reagent on the sides of the flask to the reaction mixture (to ensure all of the acid/alkali reacts)
Water doesn’t change the number of moles of reagent.