Amount of Substance Flashcards

1
Q

Relative Atomic Mass

A

Weighted average mass of an atom compared to 1/12th mass of a C-12 atom

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2
Q

Relative molecular mass

A

Weighted average mass of a molecule compared to 1/12th mass of a C-12 atom

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3
Q

Avogadro’s number

A

6 x 10^23 - number of entities in a mole

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4
Q

Mole calculation for pure solids and gases

A

n = m/ Mr

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5
Q

Mole calculation for gases

A

PV = nRT

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6
Q

Units for gas mole equation

A
P = Pa
V = m^3
T = K
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7
Q

Mole equation for solutions

A

n = cv

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8
Q

Units for solution mole equation

A
V = dm^3
C = mol dm^-3
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9
Q

Converting oC –> K

A

+ 273

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10
Q

Converting cm^3 –> dm^3

A

/ 1000

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11
Q

converting cm^3 –> m^3

A

/ 100 000

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12
Q

converting dm^3 –> m^3

A

/ 1000

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13
Q

Density equation

A

D (g cm^-3) = mass / volume

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14
Q

Empirical Formula

A

Simplest whole number ratio of atoms of each element in a compound

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15
Q

Method for empirical formula

A

Divide each mass of element by its Ar.
Divide through by the smallest number.
Find a whole number ratio without rounding

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16
Q

Molecular Formula

A

Actual number of atoms of each element in a compound

17
Q

How to find Mr on a mass spectrometer

A

The furthest peak to the right is the molecular ion peak M+

18
Q

Turn concentration in g dm^-3 to mol dm^-3

A

g dm^-3 = mol dm^-3 x Mr

19
Q

% yield

A

= actual yield / theoretical yield x 100

20
Q

% atom economy

A

mass of useful products / mass of all reactants x 100

21
Q

Rule of 1 mole of gas at RTP

A

Will have a volume of 24 dm^3. n = V/24

22
Q

Method to make a standard solution

A
  1. Weigh out required mass in weighing bottle.
  2. Tip contents into a beaker and add enough water to dissolve.
  3. Pour solution into a volumetric flask with a funnel.
  4. Wash beaker, funnel and stirring rod with water.
  5. Make solution up to the mark on flask.
  6. Invert flask several times to mix solution.
  7. Reweigh weighing bottle to calculate exact mass in flask.
23
Q

Titration method

A
  1. Rinse burette and pipette with solutions to go into them.
  2. Pipette one solution into conical flask.
  3. Fill burette making sure jet space is filled.
  4. Add a couple of drops of indicator to conical flask.
  5. Mix solutions together swirling constantly and adding dropwise near end point.
  6. Repeat titration until 2 concordant results within 0.1 of each other.
  7. Record all titre values to 2 dp
24
Q

Calculating % error

A

apparatus error/ measurement made x 100

25
Q

Total % error

A

Add all equipment errors together

26
Q

How to decrease apparatus error

A

Use equipment with a greater resolution (more dp or graduands). Increase the size of measurements i.e. scale up expt.

27
Q

% difference between actual value and calculated value

A

(actual value - calculated value) / actual value x 100