Amount Of Substance Flashcards
What does one mole contain and what is this known as?
6.02x10^23 particles known as Avogadro’s number
Does it matter what the particular are?
No they can be atoms, molecules, electrons, ions, penguins, dinosaurs- anything
Number of particles=
Number of moles x Avogadro’s number
What is 1 mole of a substance mass equal to?
It’s relative molecular mass in grand
How can you work Mr?
Number of moles =
Mass of substance/ Mr
What’s the concentration of a solution?
How many moles are dissolved per 1dm3 of solution units are mol dm^(-3)
Concentration equation
Number of moles= concentration (mol dm^(-3)) x volume dm^(-3)
1dm3=
1000cm3
To convert from cm3 to dm3?
divide by 1000
Ideal gas equation?
pV=nRT
How to convert to K
oC+ 273
Units for ideal gas equation
P= (pa) V= (m3) n= number of moles R=8.31 T= K
1cm3 is
1x10^(-6) m3
1dm3 is
1 x10^(-3) m3
Balanced equations have the same?
Number of atoms on both sides
How do you balance an equation rules?
Change number in front
DON’T CHANGE NUMBER IN FORMULA
How to balance equation?
Work out number of atoms each side
Change according
Can use 1/2 at front
Check it balances
What else can you write?
Ionic equation for any reaction involving ions happen in solution
In ionic equation only reacting particles and products formed included
Check charges balance
State symbols
S= solid L= liquid G= gas Aq= aqueous in water
Name two other things equation balancing can be used for?
Work out gas volumes
Work out masses
What do you before titration?
Make up standard solution
Explain standard solutions
Any solution you know exact concentration
Involved dissolving known amount of solid in known amount of water to create known concentration
How to make standard solution step 1?
Work out number of moles of x you need using
Moles=c/v
How to make standard solution step 2?
Work out how many grams of x needed using formula
Mass= moles x Mr
Volumes for standard solutions
Dm3
How to make standard solution step 3?
Place weighting boat on digital balance and weigh out this mass of solid. Tip into beaker and reweigh boat which may contain traces of solid. Subtract mass of boat and solid together to find precise mass of solid used
How to make standard solution step 4?
Add distilled water to beaker and stir until all x has dissolved
How to make standard solution step 5?
Tip solution into volumetric flash make sure right size for volume you’re making. Use funnel to make sure it all goes in
How to make standard solution step 6?
Rinse beaker and stirring rod with distilled water and add that to flask making sure no solute clinging to beaker to rid
How to make standard solution step 7?
Top flask up to correct volume with more distilled water. Make sure bottom of meniscus reaches line. When you get close to line add water drop by drop. If you go over you’ll have to start again.
How to make standard solution step 8?
Stopper flask and turn upside down few times to make sure mixed
What does a titration allow?
You to find out exactly how much acid is needed to neutralise measured quantity of alkali
What can you use titration information to do?
Work out concentration of alkali
Step 1 of titration
Using pipette measure out set volume of solution that you know the concentration of. Put in a flask
Step 2 of titration
Add few drops of appropriate indicator to flask
Step 3 of titration?
Fill burette with standard solution of ache remember exact concentration
Step 4 of titration?
Use funnel to carefully pour acid into burette. Always do this below eye level to avoid any avid splashing to face or eyes (wear safety specs)
Describe how to use pipette?
Pipettes measure only one volume of solution
Fill pipette to just above line and take pipette out of solution then drop level down carefully to line
Step 5 of titration
Do rough titration to get idea where end point is. Add acid to alkali using burette giving flask regular swirl
Step 6 of titration
Do accurate titration. Take initial reading to see exactly how much acid is in burette. Run acid in to within 2cm3 of end point. When at this stage add drop wise otherwise you don’t notice exactly when colour change happens and resulted won’t be accurate
Step 7 of titration
Work out amount of acid used to neutralise a alkali.
Final reading- initial reading= titre
Step 8 of titration
Repeat titration few times until three results are concordant (very similar)
Step 9 of titration
Use results from each repeat to calculate
leave anomalous results when calculating mean as can distort answer
Burettes
Measure different volumes and let you add solution drop by drop
Indicators for titrations?
Methyl orange- yellow in acid, red in alkali
Phenolphthalein- pink in alkali, colourless in acid
Indicator extra info?
Indicators change over very small pH range used so know exactly when reaction has ended
Use white tile to easily see end point
Don’t use universal indicator
Step 10 of titrations
Use mean volume to find concentration of solution in flask
Balanced equation
Work out moles of acid
Work out how many moles of alkali therefore
Work out concentration of alkali
Titration method for volumes?
Balanced equation
Work out moles of acid
Work out moles of alkali
Work out volume
Empirical formula
Simplest whole number ratio of atom of each element in a compound
Molecular formula
Gives actual numbers of atoms of each element in a compound
Molecular formula
Made up of whole number of empirical units
Empirical formula how to find
N= mass/Mr
Divide by smallest of numbers
Use ratio and put in numbers as appropriate
Can find empirical formula from?
Experiments
Theorical mass of products?
Should be found in chemical reaction
Assumes no chemicals are lost in process. Can use mass of reactants and balanced equation to find it
Actual mass of products?
Actual Yield always less than theorical Yield. Many reasons not all starting chemicals react fully, some chemicals are lost
Percentage yield=
Actual yield/ theorical yield x100
Percentage yield tells you
Tells you how wasteful process is based on product lost during process
What doesn’t percentage yield tell you?
How wasteful reaction itself is. A reaction with 100% could still be wasteful if lot of atoms from reactants wind up in by-products rather than desired products
Atom economy
Measure of the proportion of reactant atoms that become part of desired product rather than by-products in balanced chemical equation
Atom economy=
Molecular mass of desired products/ sum of molecular masses of all reactants x100
What should companies should try to use processes with?
High atom economies
Processes with high atom economies are?
Better for the environment because they produce less waste
Make more efficient use of raw materials so more substainable
Less expensive
Why is less waste good?
Any waste made needs to be disposed of safely so less made the better
Why are they more sustainable?
Use up natural resources slower
Why are they less expensive?
Company using processes with high atom economy will spend less on separating desired product from waste products and less on treating waste
How is amount of substance measured?
Using unit called the mole