amount of substance Flashcards
what is a mole?
amount of substance containing as many particles as there are C atoms in12.0g of carbon-12.
define molar mass
mass of one mole of a substance
(gmol-1)
state the ideal gas equation
pV=nRT
what is Avogadro’s Constant?
the number of atoms in 12.0g of carbon-12
6.02 x10^23
what is empirical formula?
simplest whole-number ratio of atoms of each element within a compound
what is molecular formula?
the actual number of atoms of each element within a molecule
what is the equation for the number of moles of a substance?
n=m/Mr
n= number of moles
m= mass
Mr= molecular mass
what is RTP?
293K and 101kPa
molar volume of any gas at RTP?
the volume of one mole of gas is 24.0dm3
what is avogadro’s hypothesis?
equal volumes of gases at the same temp and pressure contain equal numbers of particles
what is the equation for calculating percentage yield?
actual moles of products made/theoretical moles of product X 100
what does percentage yield measure?
efficiency of a lab or industrial preparation
what does atom economy measure?
percentage of useful products
what is the equation for calculating number of particles?
number of particles = n x Na
what is the equation for calculating molecular formula?
relative molecular mass/relative empirical formula mass X empirical formula
what is molar volume?
- the volume of one mole of gas and is the same for all gases at the same temp and pressure
- at RTP one mole of any gas occupies 24.0 dm3
what is the relationship between volume and temperature when moles and pressure are kept constant?
linear
- as volume increases, so does temp
what is the relationship between pressure and temperature if moles and volume are kept constant?
linear
- as pressure increases, so does temp
what is the relationship between pressure and volume if moles and temperature are kept constant?
- as pressure increases, volume decreases
equation for calculating moles using conc and vol
n = cv
what is concentration?
the concentration of a solution is the amount of solute (in moles) dissolved per 1 dm3 (1000cm3) of solution
what are the assumptions made about an ideal gas?
- random motion
- elastic conditions
- negligible size
- no intermolecular forces
what is stoichiometry?
the balancing numbers giving the ratio of the amount, in moles, of each substance in a balanced equation.
why is the theoretical yield so hard to achieve?
- reaction is incomplete
- competing side reactions give different products
- loss of product in handling and purification
- reversible reaction
what is the limiting reagent?
the reactant that is not in excess
what are the benefits of a high atom economy?
- produce a larger proportion of desired products and few waste products
- important for sustainability, the best use of natural resources