Amalgam Flashcards
what are amalgams two main components mixed to make the material
mix of liquid mercury and powdered silver, tin, copper and other metals
function of each material in amalgam
- silver-tin compound (react with Hg forming amalgam)
- copper (>strength & hardness)
- zinc (scavenger, oxidises and removes slag)
- Hg in powder (speeds up reaction)
- liquid Hg
particle types in amalgam and their benefits
- lathe cut
- spherical
- less Hg required
- >tensile strength
- > early compressive strength
- easier to carve
- less sensitive to condensation technique
setting reaction of amalgam
gamma phase 1 (Y1)
- first amalgam matrix molecule (Ag2Hg3)
- binds/incapsulates gamma and gamma 2 particles
- good corrosion resistance (CR)
gama phase 2 (Y2)
- second amalgam matrix molecule (Sn7Hg9)
- weak and bad CR
gamma phase (Y)
- unreacted particles (Ag3Sn)
- good Strength and CR
negative of zinc in amalgam
reacts with water to form H2 bubbles causing expansion of material
what is creep of a dental material and why bad for restorations
repeatedly applied low stresses (bellow elastic limit) causing material to flow thus permanent deformation
- causes edges of restoration to stand high, break (ditched margins) and allow microleakage
two types of amalgam and two types of the modern version
- traditional
- modern copper enriched
i. dispersion modified
ii. single composition types
Describe what ‘dispersion modified’ copper enriched amalgam is
- no gamma 2 phase also (replaced with Cu)
- spheres and lathe cut
- two reactions (dispersion modified reaction)
- silver tin forms halo around silver copper (instead of traditional Y2 SnHg formation alone)
describe what ‘single composition type’ of copper enriched amalgam is
- no gamma 2 phase also
- spherical OR Lathe cut
- copper integrated into silver tin particles
single setting reaction (single composition formulation reaction) - gamma 1 encases unreacted silver tin and copper tin (replacing gamma 2)
- strongest and least creep (BEST OVERALL)
benefits of copper enriched
- higher early strength
- less creep
- higher corrosion resistance
- > durability of margins
lifetime of amalgam restoration
4-5 years but can be >10
what material has most similar thermal expansion to dentine and enamel, but sadly has a high thermal conductivity and diffusivity
amalgam
general negatives of amalgam
- aesthetics
- mercury toxicity (env. and patient)
- no bonding (leakage)
- corrosion
- high thermal diffusivity
- local sensitivity reactions (lichenoid lesions)
- cavity prep may require excessive removal of sound tooth
- tooth discolouration
- amalgam tattoo
- galvanic response
general positives of amalgam
strong hard durable radiopaque user friendly long term quick good load bearing self setting
when use amalgam
medium to large posterior restoration