Amalgam Flashcards
advantage of dental amalgam?
IDK
disadvantage of dental amalgam?
- poor esthetics compared to resin composite
- weakening of tooth from removal of tooth structure
- recurrent carries
- no adhesive bonding, unless bonded restoration
- sensitivity of properties to manipulation
- brittle nature of material
- biocompatibility
- wastewater pollution w/ mercury
general setting reaction of amalgam?
alloy + Hg -> amalgam
Mercury/alloy ratio in dental amalgam
0.5
mercury/alloy ratio range in commercial products
IDK
List the aspects of the alloy for dental amalgam particles that control the setting process
composition
shape
size of alloy particles
List the requirements for starting alloy particle composition and properties of the resulting dental amalgam that are given in American Dental Association Standard 1.
starting alloy particle:
-The total concentration of other elements cannot exceed 0.1 wt %, unless the manufacturer provides evidence of biocompatibility
resulting alloy properties:
creep 1.0 % maximum, dimensional change between -0.15 and +0.20 %, and compressive strength minimum of 80 MPa after 1 hour and 300 MPa after 24 hours
State the two elements in greatest amount in the alloy for dental amalgam, along with other elements that are found in commercial products
2 primary elements:
Ag (primary) + Sn (secondary)
Also: 2-30% Cu and 0-1%Zn
May include: In and Pd
Comment on whether the alloy particles mixed with mercury are single-phase or contain multiple phases
3 phases
gamma (Ag3Sn)
beta (Ag-Sn)
epsilon (Cu3Sn)
how are dental amalgams classified?
2 ways:
- Method of making Particles
- Filing or lathe-cut
- spherical - composition of particles
- all particles w/ same composition
- different composition
Describe the size range of the particles and the importance of this size range for condensation
of the dental amalgam mix
range:
- spherical particles range from 50micrometer diameter to over an order of magnitude smaller
- lathe-cut: wide range in sizes
intentionally done by manufacurer for optimum condensation
Explain the difference in mercury to alloy ratio that is needed for spherical alloy particles vs. lathe cut alloy particles.
spherical particles have lower mercury/alloy ratio than lathe cut
which one resists more force of condensation, spherical or lathe-cut?
lathe-cut
amalgam classification based on composition of particles?
- high copper vs low copper
2. zinc containing vs zinc free
high copper vs low copper, which one is better, why?
high copper bcz:
greater longevity
lower creep
zinc containing vs zinc free, which one is better? why?
either:
- zinc improves corrosion resistance
- if zinc, then less plastic amalgam mix
what’s used in OSU?
60% spherical (50Ag, 30Sn, 20Cu, 0.5Pd)
40% lathe-cut (57Ag, 30Sn, 14Cu)
the product is classified as: fast, regular and slow setting time and ECT.
relation btwn setting time and mercury/alloy ratio
slower setting times correspond to higher mercury/alloy ratio
why proprietary heat treatment?
- eliminate compositional nonuniformaty
- relieves stresses in alloy particles
- provide manufacturer control of setting time (IMPORTANT)
General form of setting rxn
gamma (starting alloy particles) + Hg (liquid) -> rxn phases (matrix) + unreacted particles (core)
rxn of low copper amalgam
alloy (gamma) + Hg -> gamma 1 + gamma 2 + unreacted alloy particles
rxn of high copper amalgam
alloy (gamma) + Hg –> gamma 1 + n’ + unreacted alloy particles
what’s present in both high copper and low copper amalgam?
gamma 1