Alloys for Metal Resotrations Revision Questions Flashcards
Procelain Characterstics
rigid - large stress required to cause strain
hard - surface withstands abrasion
strong - high compressive strength, low tensile strength
form surface defects - leads to fracture at low stress
brittle/low fracture toughness - 0.1% before fracturing
Examples of porcelain metal restorations
high and low gold alloy
silver palladium
nickel palladium
cobalt chromium
Mechanical properties of porcelain metal restiorations
good hardness
good bond strength
want high elastic modulus
melting/recrystalisation temp - alloys higher than procelain so creep does not occur
Characterstics of alloy bond to porcelain
form good bond to porcelain (good wetting)
thermal expansion coeffiecent similar
avoid discolouration of porcelain - no copper in high gold alloy
Modes of failure in porcelain fused resotrations
oxide layer fracturing
oxide layer delaminating from alloy
porcelain detaching from oxide layer
Bond between oxide layer, alloy and porcelain
Mechanical - due to irregularities on surface of alloys and porcelain causing interlocking
Stressed skin effect - during production process after furnance stage the alloy contracts slightly more on cooling and generates compressive forces on porcelain
Chemical - oxides in the metal oxides coating on the alloy migrating with oxides on the porcelain itself. occurs during firing stage where high temps reached (electron sharing)
High gold alloys
80% gold, 1% silver, 14% platinium
small amount of indium/tin
platinium/palladium - helps match thermal expansion and increases melting point
disadvatnages - mp too low, young’s modulus too low (not rigid)
Low gold alloys
50% gold, 30% palladium, 10% silver, 10% indium/tin
increased melting temp
better mechanical propterties than high gold
silver palladium
30% silver, 60% palladium
high melting temp
casting a challenge
Nickel chromium
70-80% nickel, 10-25% chromium
high melting point and young’s modulus
disadvatanges - high casting shrinkage, low bond strength to porcelain
Cobalt Chromium
advatanges - high EM, hard material, high tensile strength, high MP
Disadvantges - low bond strength, significant shrinkage during casting - challenging