all reagents and conditions Flashcards

1
Q

carboxylic acid —> acyl chloride

A

SOCl₂

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2
Q

acyl chloride —> carboxylic acid

A

H₂O

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3
Q

haloalkane —> nitrile

A

ethanolic KCN

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4
Q

aldehyde/ketone —> hydroxynitrile

A

KCN/H+ (aq) OR HCN (aq)

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5
Q

benzene —> aromatic ketone

A

acyle chloride/AlCl₃

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6
Q

phenol —> nitrophenol

A

HNO₃ (2,4,6)

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7
Q

alkane —> monohaloalkane

A

X₂ /UV

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8
Q

alkene —> dihaloalkane

A

X₂

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9
Q

alkene —> monohaloalkane

A

HX

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10
Q

alcohol —> monohaloalkane

A

NaX/H₂SO₄ (HX made insitu)

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11
Q

benzene —> halobenzene

A

Cl₂/AlCl₃ OR Br₂/FeBr₃

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12
Q

phenol —> bromophenol

A

Br₂

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13
Q

nitrobenzene —> phenyl amine

A

Sn/ conc HCl

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14
Q

alkene —> alkane

A

H₂/Ni

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15
Q

1º alcohol —> aldehyde

A

Cr₂O₇²⁻/H+, heat under distillation

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16
Q

1º alcohol —> carboxylic acid

A

Cr₂O₇²⁻/H+, heat under reflux

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17
Q

2º alcohol —> ketone

A

Cr₂O₇²⁻/H+, heat under reflux

18
Q

aldehyde —> carboxylic acid

A

Cr₂O₇²⁻/H+, heat under reflux

19
Q

aldehyde —> 1º alcohol

A

NaBH₄ (aq)

20
Q

ketone —> 2º alcohol

A

NaBH₄ (aq)

21
Q

nitrile —> amine

22
Q

haloalkane —> alcohol

A

NaOH (aq), heat under reflux

23
Q

carboxylic acid —> carboxylate salt (-oate)

24
Q

acyl chloride —> 1º amide

A

excess NH₃

25
ester ---> carboxylate salt + alcohol
MOH (aq), heat
26
haloalkane ---> 1º amine
ethanolic NH₃ (or excess)
27
amide ---> carboxylate salt + amine
MOH (aq), heat
28
phenol ---> sodium phenoxide
NaOH (aq)
29
carboxylic acid ---> ester
alcohol/conc H₂SO₄
30
alcohol ---> ester
carboxylic acid/conc H₂SO₄
31
acyl chloride ---> 2º amide
excess 1º amine
32
phenol ---> ester 1
acyl chloride
33
phenol ----> ester 2
acid anhydride
34
benzene ---> alkyl benzene
haloalkane/AlCl₃
35
haloalkane ---> alcohol
H₂O/AgNO₃
36
alkene ---> alcohol
H₂O(g) /H₃PO₄
37
alcohol ---> alkene
H₃PO₄ OR H₂SO₄ , heat
38
ester ---> carboxylic acid + alcohol
H⁺ (aq) , heat
39
amide ---> carboxylic acid + amine
H⁺ (aq) , heat
40
amine ---> amine salt
HCl (aq)
41
nitrile ---> carboxylic acid
HCl (aq) OR H⁺ (aq) & H₂O
42
benzene ---> nitrobenzene
conc HNO₃/conc H₂SO₄