All Enthalpy Definitions Flashcards
The basic enthalpy stuff, definitions, etc
Enthalpy change of formation
Enthalpy change when one mole of a compound is formed from its constituent elements under standard conditions
Standard conditions
298K at 100kPa
Enthalpy change of combustion
Enthalpy change when one mole of a compound undergoes complete combustion in excess oxygen under standard conditions
Enthalpy change of neutralisation
Enthalpy change when one mole of water is formed in a reaction between an acid and alkali under standard conditions
First ionisation enthalpy (or first ionisation energy)
Enthalpy change when one mole of gaseous atoms loses one mole of electrons to form one mole of gaseous 1+ ions
Second ionisation enthalpy (or second ionisation energy)
Enthalpy change when one mole of gaseous 1+ ions loses one mole of electrons to form one mole of gaseous 2+ ions
First electron affinity
Enthalpy change when one mole of gaseous atoms gains one mole of electrons to form one mole of gaseous 1- ions
Second electron affinity
Enthalpy change when one mole of gaseous 1- ions gains one mole of electrons to form one mole of gaseous 2- ions
Enthalpy of atomisation
Enthalpy change when one mole of gaseous atoms is produced from an element under standard conditions
Hydration enthalpy
Enthalpy change when one mole of gaseous ions become dissolved in water
Enthalpy of solution
Enthalpy change when one mole of ionic solid is dissolved in enough water so that the dissolved ions are well separated and do no interact with each other
Bond dissociation enthalpy
Enthalpy change when one mole of covalent bonds in gaseous molecules are broken
Lattice enthalpy of formation
Enthalpy change when one mole of solid ionic compound is formed from its constituent gaseous ions
Lattice enthalpy of dissociation
Enthalpy change when one mole of solid ionic compound is broken into its constituent gaseous ions
Enthalpy of vaporisation
Enthalpy change when one mole of liquid is turned into a gas