All Enthalpy Definitions Flashcards

The basic enthalpy stuff, definitions, etc

1
Q

Enthalpy change of formation

A

Enthalpy change when one mole of a compound is formed from its constituent elements under standard conditions

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2
Q

Standard conditions

A

298K at 100kPa

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3
Q

Enthalpy change of combustion

A

Enthalpy change when one mole of a compound undergoes complete combustion in excess oxygen under standard conditions

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4
Q

Enthalpy change of neutralisation

A

Enthalpy change when one mole of water is formed in a reaction between an acid and alkali under standard conditions

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5
Q

First ionisation enthalpy (or first ionisation energy)

A

Enthalpy change when one mole of gaseous atoms loses one mole of electrons to form one mole of gaseous 1+ ions

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6
Q

Second ionisation enthalpy (or second ionisation energy)

A

Enthalpy change when one mole of gaseous 1+ ions loses one mole of electrons to form one mole of gaseous 2+ ions

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7
Q

First electron affinity

A

Enthalpy change when one mole of gaseous atoms gains one mole of electrons to form one mole of gaseous 1- ions

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8
Q

Second electron affinity

A

Enthalpy change when one mole of gaseous 1- ions gains one mole of electrons to form one mole of gaseous 2- ions

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9
Q

Enthalpy of atomisation

A

Enthalpy change when one mole of gaseous atoms is produced from an element under standard conditions

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10
Q

Hydration enthalpy

A

Enthalpy change when one mole of gaseous ions become dissolved in water

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11
Q

Enthalpy of solution

A

Enthalpy change when one mole of ionic solid is dissolved in enough water so that the dissolved ions are well separated and do no interact with each other

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12
Q

Bond dissociation enthalpy

A

Enthalpy change when one mole of covalent bonds in gaseous molecules are broken

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13
Q

Lattice enthalpy of formation

A

Enthalpy change when one mole of solid ionic compound is formed from its constituent gaseous ions

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14
Q

Lattice enthalpy of dissociation

A

Enthalpy change when one mole of solid ionic compound is broken into its constituent gaseous ions

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15
Q

Enthalpy of vaporisation

A

Enthalpy change when one mole of liquid is turned into a gas

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16
Q

Enthalpy of fusion

A

Enthalpy change when one mole of solid is turned into a liquid