All Cards Lol Sorry Flashcards

1
Q

Grignard + CO2

A

Forms carboxylic acid

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2
Q

Grignard + aldehyde

A

Produces secondary alcohol and tertiary alcohols with ketones

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3
Q

Grignard + methanal

A

Produces primary alcohol

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4
Q

How to form grignard reagant

A

Halogenoalkane is dissolved in dry ether and reacted with magnesium

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5
Q

Zwitterion in acidic solution

A

H3N+ and CO2H

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6
Q

Zwitterion in alkaline solution

A

H2N and CO2-

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7
Q

Amine + acid

A

= ammonium salt

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8
Q

Amide functional group?

A

Double Bond to O

NH2

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9
Q

Define rate of reaction

A

Change in concentration of a substance in unit time

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10
Q

Nitration of benzene

A

HNO3 + 2H2SO4 ->. NO2+ + 2HSO4- + H3O+

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11
Q

Acyl chloride + amine

A

Secondary amide

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12
Q

Acyl chloride + NH3

A

Primary amide + NH4Cl

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13
Q

Acyl chloride + alcohol

A

Ester + HCl

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14
Q

Acyl chloride + H2O

A

Carboxylic acid + HCl

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15
Q

Acid + metal

A

Salt and hydrogen

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16
Q

Acid + alkali

A

Salt and water

17
Q

Acid + carbonate

A

Salt and water and co2

18
Q

Define nucleophile

A

Electron pair donator

19
Q

Define electrophile

A

An electron pair acceptor

20
Q

Formation of pi bond

A

Formed by sideways overlap of two p orbitals on each carbon atom.
Pi Bond weaker than sigma bond

21
Q

Formation of sigma bond

A

One sp2 orbital from each carbon overlap to form a single c-c bond
Rotation can occur around sigma bond

22
Q

Carbonyl + I2 + NaOH

A

Yellow crystalline ppt and antiseptic smell

23
Q

Test for acyl chloride

A

AgNO3, steamy fumes of HCl and white ppt of AgCl

24
Q

Test for chloroalkane

A

Warm AgNO3, white ppt of AgCl

25
Test for primary secondary alcohols
Na2Cr2O7/H2SO4 Orange to green
26
Test for carboxylic
NaCO3 effervescence is CO2
27
Test for aldehyde
Tollens silver mirror, feelings shows blue solution to brick red ppt
28
Test for carbonyls
2,4-DNP, orange ppt
29
Test for alcohols, phenols and carboxylic
Sodium metal, effervescence (H2 gas)
30
Test for alcohol and carboxylic acid
PCl5, misty fumes of HCl
31
Test for alkenes
Br water, orange to colourless
32
Functional group ester
- C - O - || O