All Cards Lol Sorry Flashcards
Grignard + CO2
Forms carboxylic acid
Grignard + aldehyde
Produces secondary alcohol and tertiary alcohols with ketones
Grignard + methanal
Produces primary alcohol
How to form grignard reagant
Halogenoalkane is dissolved in dry ether and reacted with magnesium
Zwitterion in acidic solution
H3N+ and CO2H
Zwitterion in alkaline solution
H2N and CO2-
Amine + acid
= ammonium salt
Amide functional group?
Double Bond to O
NH2
Define rate of reaction
Change in concentration of a substance in unit time
Nitration of benzene
HNO3 + 2H2SO4 ->. NO2+ + 2HSO4- + H3O+
Acyl chloride + amine
Secondary amide
Acyl chloride + NH3
Primary amide + NH4Cl
Acyl chloride + alcohol
Ester + HCl
Acyl chloride + H2O
Carboxylic acid + HCl
Acid + metal
Salt and hydrogen
Acid + alkali
Salt and water
Acid + carbonate
Salt and water and co2
Define nucleophile
Electron pair donator
Define electrophile
An electron pair acceptor
Formation of pi bond
Formed by sideways overlap of two p orbitals on each carbon atom.
Pi Bond weaker than sigma bond
Formation of sigma bond
One sp2 orbital from each carbon overlap to form a single c-c bond
Rotation can occur around sigma bond
Carbonyl + I2 + NaOH
Yellow crystalline ppt and antiseptic smell
Test for acyl chloride
AgNO3, steamy fumes of HCl and white ppt of AgCl
Test for chloroalkane
Warm AgNO3, white ppt of AgCl