all Flashcards

1
Q

Acid

A

a species that releases H+ ions in aqueous solution.

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2
Q

Acid dissociation constant Ka

A

The equilibrium constant that shows the extent of dissociation of a weak acid
for a weak acid: Ka = [H+(aq)] x [A-(aq)] / [HA(aq)]

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3
Q

Acid-base pairs

A

A pair of two species that transform into each other by gain or loss of a proton

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4
Q

Activation energy

A

the minimum energy required to start start a reaction by the braking of bonds

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5
Q

actual yield

A

the amount of product obtained from a reaction

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6
Q

addition polymerisation

A

formation of a very long molecular chain, by repeated addition reactions of many unsaturated alkene molecules

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7
Q

addition reaction

A

a reaction in which a reactant is added to an unsaturated molecule to form a saturated molecule

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8
Q

adsorption

A

the process that occures when or gas or liquid or solute is held to the surface of a solid. often used to speed up reactions

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9
Q

alicyclic

A

containing carbon atoms joined in a ring but is not aromatic

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10
Q

aliphatic

A

containing carbon atoms joined together in straight or branched chains

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11
Q

alkali

A

a type of base that when dissolved in water forms a hydroxide ion (OH-)

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12
Q

alkanes

A

general formula of Cn H2n+2

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13
Q

amount of substance

A

the quantity whose unit of the mole, used as a means of counting any species such as atoms, ions and molecules

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14
Q

anhydrous

A

containing no water molecules

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15
Q

anion

A

a negatively charged ion with more electrons than protons

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16
Q

Aromatic

A

cyclic hydrocarbons containing one or more benzene ring

17
Q

atom economy

A

(sum of molar masses of the desired product)/(sum of molar masses of all products)

18
Q

Atomic number

A

the number of protons in the nucleus of an atom

19
Q

Atomic orbitals

A

a region of space around the nucleus that can hold up to two electrons with opposite spins

20
Q

average bond enthalpy

A

the average enthalpy change that takes place when breaking, by homolytic fission, 1 mole of a given type of bond in the molecules of a gaseous species

21
Q

Avogadro’s constant

A

the number of atoms per mole of carbon-12 (6.02x10^23)

22
Q

base

A

a compound that neutralises an acid to form a salt

23
Q

bond angles

A
the angle between two bonds at an element. notable ones include: 
tetrahedral, 109.5
pyramidal, 107
non-linear, 104.5
trigonal planar, 120
linear, 180
24
Q

bond dissociation energy

A

the same as average bond enthalpy word for word…. but without average

25
Q

bonded pair

A

a pair of electrons shared between two atoms to make a covalent bond

26
Q

Bronsted-Lowry acid

A

a species that that is a proton, H+, donor

27
Q

Bronsted-Lowry base

A

a species that is a proton acceptor

buffer solution

28
Q

buffer solution

A

a system that minimises pH change on the addition of a small amount of acid or base

29
Q

carbocation

A

an ion that contains a positively charged carbon atom

30
Q

catalyst

A

a substance that increases the rate of a chemical reaction without being used up in the process; a catalyst provides an alternative route for the reaction with lower activation energy

31
Q

cation

A

a positively charged ion with fewer electrons than protons

32
Q

chain reaction

A

a reaction in which the propagation steps release new radicals that continue the reaction

33
Q

cis-trans isomerism

A

a special type of E/Z isomerism in which there are two non-hydrogen groups and two hydrogen atoms around the C=C double bond: the cis isomer [Z isomer] has H atoms on each carbon on the same side. The trans isomer [E isomer] has the opposite.

34
Q

closed system

A

A system isolated from its surroundings