Alkenes Flashcards

1
Q

What are Alkenes ?

A
  • unsaturated hydrocarbons
  • general formular CnH2n
  • they can be branched, contain more than one double bond, or cyclic
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Define unsaturated hydrocarbon

A
  • contain a multiple carbon to carbon bond

- so does not contain the maximum number of hydrogen atom

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Describe what a C=C bond contains

A
  • one sigma bond

- one pi bond

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

How is a sigma bond formed ?

A
  • two sp^2 orbitals overlap
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

How are pi bond formed ?

A
  • the sideways overlap of two p orbitals on each carbon atom

- forming a pi bond above and below the plane of the molecule

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Where is the electron density in pi bond concentrated?

A
  • above and below the sigma bond joining the nuclei of the bonding atoms
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Which bond is stronger ?

A
  • sigma bonds as there is more overlap of orbital paths
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

What do pi bond prevent ?

A
  • rotation about the double bond

- as it locks the two carbon atoms in a fixed position

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What is the shape around each carbon tom involved in the double bond ?

A

TRIGONAL PLANAR

  • three regions of electron density around each carbon atom
  • the three regions repel each other as far as possible
  • so has a bond angle of 120
How well did you know this?
1
Not at all
2
3
4
5
Perfectly