Alkenes Flashcards

1
Q

What is stereoisomerism?

A

Compounds with the same structural formula but the atoms are pointing in a different direction in space

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2
Q

What is E/Z isomerism?

A

A type of isomerism and a type of stereoisomerism that occurs in alkenes due to no rotation in a double carbon bond

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3
Q

In which type of compounds does E/Z isomerism occur?

A

Alkenes

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4
Q

Why can’t alkenes rotate like alkanes?

A

There is no rotation in a double carbon bond

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5
Q

What is the Z isomer?

A

Isomer where both atoms are on the ‘same’ side of the carbon

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6
Q

How do you determine if an isomer is Z?

A

If the atoms bonded to the carbon with the highest priority (highest atomic number) are on the same side

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7
Q

What is the E isomer?

A

The isomer where the highest priority atoms are on opposite sides

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8
Q

How do you name an E/Z isomer?

A

Put a ‘Z’ or ‘E’ at the front when naming the alkene, treating E or Z like a number with a dash (-) after it

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9
Q

Provide an example of an alkene that can exist as E/Z isomers.

A

But-2-ene can exist as Z-but-2-ene or E-but-2-ene

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10
Q

What condition must be met for E/Z isomers to occur?

A

Both carbons in the double carbon bond must have two different atoms or groups attached

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11
Q

True or False: All alkenes have E/Z isomers.

A

False

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12
Q

What is addition polymerisation?

A

Addition polymerisation is the process where monomers are joined together to form a polymer.

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13
Q

What is a polymer?

A

A polymer is a large molecule made up of many repeating units called monomers.

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14
Q

What happens during the formation of an addition polymer?

A

During the formation of an addition polymer, the double bonds in alkenes break and the alkenes join together in a chain.

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15
Q

What is represented by the notation C=C?

A

C=C represents the double bond between carbon atoms in alkenes.

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16
Q

What does the symbol ‘n’ signify in the context of polymers?

A

‘n’ signifies the number of alkenes that are joined together to form the polymer.

17
Q

How do you denote a polymer made from an alkene?

A

To denote a polymer made from an alkene, you write the name of the polymer in front of the alkene.

18
Q

What is the environmental impact of recycling polymers?

A

Recycling reduces the environmental impact of discarded polymers by preventing them from ending up in landfills.

19
Q

What are the steps involved in recycling polymers?

A

Discarded polymers are sorted, chopped, washed, dried, and then melted.

20
Q

What happens to recycled polymers after processing?

A

The recycled polymer is then sold for further use.

21
Q

What is a hazard associated with recycling PVC?

A

Recycling PVC can release hydrogen chloride, a corrosive gas.

22
Q

Why are some polymers difficult to recycle?

A

Some polymers are difficult to recycle because they are derived from petroleum.

23
Q

What is one method of waste management for non-recyclable polymers?

A

Non-recyclable polymers can be incinerated to produce heat and generate steam.

24
Q

What can be generated from incinerating waste polymers?

A

Incinerating waste polymers can generate electricity for the national grid.

25
Q

What is feedstock recycling?

A

Feedstock recycling is a chemical and thermal process that reclaims monomers, gases, or oil to reuse and make new products from waste polymers.

26
Q

How can feedstock recycling benefit crude oil production?

A

The materials reclaimed through feedstock recycling can be used as raw materials for the production of new polymers in refineries.

27
Q

What is a major advantage of feedstock recycling?

A

A major advantage of feedstock recycling is that it is able to handle unsorted and unmixed polymers.

28
Q

What are biodegradable polymers?

A

Biodegradable polymers are broken down by microorganisms into water, carbon dioxide, and organic compounds.

29
Q

What are biodegradable polymers typically made from?

A

They are usually made from starch or cellulose, or contain additives that alter the structure of traditional polymers.

30
Q

What are compostable polymers?

A

Compostable polymers leave no toxic residue and are based on polylactic acid.

31
Q

What are some examples of products made from compostable polymers?

A

Examples include plates and cups made of sugar cane fiber, which are replacing traditional plastic products.

32
Q

What are photo degradable polymers?

A

Photo degradable polymers are plant-based polymers that can degrade when exposed to light.

33
Q

How do photo degradable polymers start degradation?

A

They contain bonds that are weakened by absorbing light to start degradation.

34
Q

What are light-absorbing additives used for?

A

Light-absorbing additives are used in the development of photo degradable polymers.

35
Q

What are the four reactions that occur with alkenes

A

Hydrogenation, Halogenation, Hydrogenation, Hydration reactions

36
Q

What conditions do you need for hydrogenation, what does this make

A

Needs to be passed through a nickel catalyst at a temperature of 150°C. It is used to make saturated oil (margarine)

37
Q

What are the conditions needed for the hydration of alkenes

A

Alkenes react with steam. In the presence of a phosphoric acid (H₃PO₄)with high temp of 300°C and 60atm

38
Q

What are the dangers of consuming saturated fats

A

They cause heart disease