Alkenes Flashcards
Two types of bonds formed by the overlapping of orbitals in ethene
Sigma bonds (σ)
Pi bonds (π)
Sigma bonds (σ) in ethene
Each carbon atom uses three of its four electrons to form Sigma bonds
Two between the hydrogen and carbon
One between the double bonded carbon
Pi bonds (π) in ethene
The fourth electron from each carbon atom occupies a p orbital which overlaps sideways with another p-orbital to form a pi bond
This means that the C-C double bond is
One pi bond and one sigma bond
Bond angles around carbon atom
120 degrees ( 3 bonding pairs )
Why cant ethene or other alkenes rotate
Pi bonds cant rotate because any rotation would reduce the overlap of the p orbitals
Effect of alkenes not being able to rotate
The structure of alkenes across the double bond is effectively locked