ALKENES Flashcards

1
Q

What is a homologous series

A

Organic compounds with the same functional group

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2
Q

What is a functional group

A

Reactive part of an organic molecule: Alkenes: C=C bonds makes them more reactive than an alkane

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3
Q

General formula for alkanes and alkenes

A

Alkane: CnH2n+2

Alkene: CnH2n

N= no. of carbons

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4
Q

What does combustion produce

A

Carbon dioxide and water

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5
Q

Why does the combustion of alkenes produce a sootier flame than an alkane

A

Incomplete combustion producing carbon particulates

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6
Q

Conditions for hydrogenation

A

Nickel catalyst, 150*C

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7
Q

Conditions for hydration

A

Phosphoric acid catalyst, Steam 300*C

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8
Q

Testing alkanes and alkenes with bromine water

A

Alkanes: stay orange-brown
Alkenes: orange brown to colourless (not Clear)

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9
Q

What is hydrogenation?

A

Saturating the alkene, converting double bonds into single bonds

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10
Q

What is combustion? (Of an alkene)

A

A chemical reaction where the alkene reacts with oxygen to produce CO2 and H2O and energy

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11
Q

What is hydration? (Of an alkene)

A

A chemical reaction where water is added to an alkene to form an alcohol, breaks down the double c bond, adds an -OH group to one carbon and a hydrogen atom to the other

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12
Q

What’s a haloalkane

A

A haloalkane is an organic compound where one or more hydrogen atoms in an alkane are replaced by a halogen atom (fluorine, chlorine, bromine, or iodine).

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13
Q

What are the first four alcohols in the homologous series

A

Methanol ethanol propanol butanol

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14
Q

What’s the functional group of alcohols

A

the OH

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15
Q

What ending goes with alcohols

A

anol

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16
Q

3 main uses of alcohols

A

Fuels
Solvents
Alcoholic drinks

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17
Q

How to alcohols react with oxygen

A

Burn well, combust, oxidised to carboxylic acids slowly by mild oxidant agents

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18
Q

Ethanol + oxygen =

(For complete combustion)

A

Carbon dioxide + water

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19
Q

Ethanol + oxygen=

(For incomplete/partial combustion)

A

Ethanoic acid + water

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20
Q

How does alcohol react with sodium

A

Fizzes (producing H2 gas)

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21
Q

Ethanol + sodium =

A

Sodium ethoxide + hydrogen

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22
Q

Relationship between alcohols solubility and the no. carbon atoms

A

Alcohols with small carbon chains are soluble in water and form neutral solutions. However, as the number of carbon atoms in the alcohol increases, solubility in water decreases.

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23
Q

How do alcohols react with carboxylic acid

A

Carboxylic acids react with alcohols in the presence of a concentrated sulfuric acid (H_2SO_4) catalyst to form esters.

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24
Q

Ethanoic acid + ethanol =
Carboxylic acid + alcohol =

A

Ethyl ethanoate
Ester + H2O

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25
Chemical formulas of glucose
C6H12O6
26
Fermentation of sugar cane is a method of making alcohol, what conditions are needed
Yeast catalyst Anaerobic (if O2 is added it forms carboxylic acid) Temp 30-40 degrees (at lower temp, rate of reaction too slow, higher temps can make yeast denature which stops the reaction)
27
You can make alcohol by adding Ethene to H2O, what are the conditions
Phosphoric acid catalyst Steam 300 degrees
28
What is biofuel
A renewable fuel made from plant material or animal waste
29
Glucose = ethanol + carbon dioxide is the equation for what
Fermentation of sugar cane
30
Advantages of using the fermentation method to create alcohol
Renewable Doesn’t require as much energy
31
Disadvantages of using the fermentation method to create alcohol
Land for plants instead of crops Need time for plants to grow Batch process with multiple steps Ethanol is aqueous
32
Meaning of aqueous
Dissolved in water or containing water
33
Advantages of using the Ethene method to create alcohol
Continuous process: quick Only one product formed (no waste) Ethanol is pure
34
Disadvantages of using the Ethene method to create alcohol
Non renewable (from crude oil) Requires lots of energy
35
What’s the functional group of carboxylic acid and what is the word ending What are the first four carboxylic acids
COOH oic acid Methanoic acid, ethanoic acid, propanoic acid, butanoic acid,
36
What’s the observation and conclusion for the reaction of water and carboxylic acid
Miscible in water (unusual for organic compounds) Mix with water to form a weakly acidic solution
37
What’s the observation and conclusion for the reaction of carbonate and carboxylic acid
Fizzing React with sodium hydrogen carbonate to produce carbon dioxide gas
38
What’s the observation and conclusion for the reaction of ethanol and carboxylic acid
Aroma Butyl ethanoate (also in pears) sweet smelling ester is formed
39
Meaning of miscible
Two substances can mix together to form a homogeneous solution (dissolve into each other without forming separate layers)
40
Carboxylic acids are ____ acids so partially ______
Weak Ionise
41
Functional group of esters and what’s the word ending
COO alkyl - - oate
42
Name one ester
Ethyl ethanoate
43
Polymers are m__________. They are a formation of _____ _________ molecules from lots of ______ molecules joining together.
Macromolecules Long chain Small
44
What are the two types of polymers and tell me about their products
Addition: with no other products Condensation: with another small molecule (e.g water) produced as well
45
What are the three types of structures when talking about polymers?
Monomer structure Polymer structure Repeating unit
46
What must you always do before converting an Alkene into a polymer in an equation
Rearrange the alkene into the correct format
47
What is thermosoftening?
• individual chains intertwined • weak forces between chains • melt and remold
48
What is thermosetting
• form cross links between chains and held in solid structure • hard and rigid • do not soften when heated
49
What does phenylethene make
Polystyrene
50
What does chloroethene make
PVC
51
What does tetrafluoroethene make
PTFE/Teflon
52
What does methyl 2-cyanopropenoate make
Superglue
53
What does methyl propenoate make
Perspex
54
Uses of polystyrene, PVC, Teflon/PTFE, superglue, Perspex (These are all products of addition polymers)
Polystyrene: insulation, packaging materials PVC: plumbing pipes, electrical cable insulation Teflon/PTFE: non stick coatings, Industrial lubricants Superglue: bonding materials, medical applications Perspex: windows, protective screens
55
Terylene (a polyester) makes what? What’s it used for?
PET Plastic bottles, containers, clothing fibres
56
Nylon, Kevlar and amino acids are examples of polyamides. Give the uses of each one
Nylon: clothing fabrics, ropes Kevlar: bullet proof vests, strong rope Amino acids: form proteins
57
Describe a polyester reaction
Dicarboxylic acid and diol join H20 is removed Ester link is formed
58
What do shapes represent in a condensation polymer reaction
Groups of atoms between the functional groups
59
What’s the functional group of an Ester
COO
60
Describe a polyamide reaction
Dicarboxylic acid and diamine Lose H20 Peptide link formed
61
What’s the functional group for a polyamide reaction?
CONH
62
What’s the difference between a polyamide reaction and a polyester reaction?
Polyamide: peptide link (CONH) Polyester: ester link (COO)
63
What’s the difference between addition and condensation polymers?
Addition polymer doesn’t produce any other products
64
A carbonate + a carboxylic acid =
A salt, carbon dioxide and water
65
What’s the monomer and polymer of carbohydrates
M: Glucose P: Starch and sugar
66
What’s the monomer and polymer of proteins
M: amino acids P: polypeptide (polyamide)
67
4 examples of naturally occurring proteins
Enzymes Haemoglobin Antibodies Body tissues
68
What are the two groups making up amino acids
Amine group Carboxylic acid group
69
What’s the role of DNA
Hold genetic information in the nucleus
70
What is dna made up of
2 polymer chains which form a double helix 4 different monomers called nucleotides
71
Name the four nucleotides (CGAT)
Cytosine Guanine Adenine Thymine
72
Ethene + water (steam) = ethanol is the equation for what
Making alcohol using ethene