Alkene Reactions Flashcards
1
Q
- BH3
- NaOH
A
Hydroboration - alcohol
Anti-Markovnikoff
syn addition
2
Q
- Hg(OAc)2
H2O - NaBH4
A
Oxymercuration - alcohol
Markovnikoff
syn + anti
3
Q
- H2SO4
- H2O
A
Acid-catalyzed addition of H2O - alcohol
Markovnikoff
syn + anti
4
Q
HCl
A
Addition of HX - halogen
Markovnikoff
syn + anti
5
Q
- Br2
or - Br2
- H2O
A
Bromination - bromine
N/A
anti-addition
Markovnikoff - alcohol and halogen
anti addition
6
Q
Cl2
A
Chlorination - 2 chlorine
N/A
anti addition
7
Q
OsO4
A
Dihydroxylation -dialcohol
N/A
syn addition
8
Q
KMnO4
cold, dilute
A
Dihydroxylation - dialcohol
N/A
syn addition
9
Q
RCOO . OH
A
Epoxidation - epoxide
N/A
syn addition
10
Q
- H2
- Pd/ C
A
Hydrogenation - hydrogen
N/A
syn addition
11
Q
- HBr
- peroxides (RO-OR)
A
Radical addition of HBr - H and Br
anti-Markovnikoff
syn+ anti
12
Q
- O3
- CH3-S-CH3 (or Zn/H+)
A
Ozonolysis (reductive workup)
aldehyde and ketone
13
Q
- O3
- H2O2
A
Ozonolysis (oxidative workup)
Ketone and carboxylic acid
14
Q
- CH2I2
- Zn/Cu
A
Chloropropanation cyclopropane
N/A
syn addition
