Alkene Reactions Flashcards
1
Q
HX
A
HX Addition
Mark
2
Q
HX (R present)
A
HX Addition
Mark; hydride or methyl shift
3
Q
- HBr
- R-O-O-R
A
Anti Mark HX addition
Anti Mark; radical mechanism
4
Q
H3O+ (w/ catalyst)
A
Hydration
Mark
5
Q
HX (R present)
A
HX Addition
Mark; hydride/methyl shift
6
Q
- Hg(OaC)2, H2O
- BaNH4
A
Oxymercuration/Demercuration
Mark; 3 member
7
Q
- BH3, THF
- H2O2, (+)OH-
A
Hydroboration/Oxidation
Anti Mark;
Syn addition
transition state
8
Q
- X2
- CHnXm
A
Halogenation
Anti addition
9
Q
- X2
- ROH
A
Halogenation
Mark (alcohol/ether); 3 member
10
Q
McPBA
A
Epoxidation
Meso
O
11
Q
- H2
- Pt, Ni, Pd/c
A
Hydrogenation
syn addition
racemic (enan)
12
Q
- KMnO4
- cold, OH-
A
Hydroxylation
syn addition
racemic (enan)
13
Q
- O3
- DMS
A
Ozonolysis
reducing (H)
14
Q
- O3
- H2O2
A
Ozonolysis
oxidizing (OH)
15
Q
Trans
A
opposite
