Alkanes Flashcards

1
Q

What is the general formula for an alkane?

A

CnH2n+2 e.g. C2H6, C3H8

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2
Q

Are they saturated or unsaturated?

A

Saturated as they contain no C=C bond.

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3
Q

Polar or non-polar?

A

Non polar

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4
Q

What are the only forces of attraction between neighbouring molecules?

A

Van der Waals

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5
Q

What happens as chain length increases?

A

Boiling point increases as the Van der Waals forces of attraction between the molecules increases. The viscosity increases.

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6
Q

What happens when they become branched?

A

The more branching there is the lower the boiling point, because there are less Van der Waals forces between the molecules as they cannot pack as tightly together.

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7
Q

What is combustion? Complete and incomplete?

A

Combustion if the chemical reaction of a fuel with oxygen releasing heat and forming oxides.
Complete - Plentiful supply of O2
Incomplete - Limited supply of O2

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8
Q

What does the complete combustion form

A

Carbon Dioxide and Water

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9
Q

What does the incomplete combustion form

A

Carbon monoxide and water and soot

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10
Q

What colour do compounds with a high % carbon burn

A

Smoky orange flame

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11
Q

What colour do compounds with a low % carbon burn

A

Clean blue

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12
Q

How is the temperature of the earth raised?

A

Greenhouse gases absorb infrared radiation emitted from the earths surface and reflect it back to earth.

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13
Q

What are the effects of this raised temperature?

A

Climate change, increased sea levels, melting of polar ice caps and flooding of low-level regions.

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14
Q

What method are used limit the production of greenhouses gases?

A

1) Removing Sulfur from fuels before combustion
2) Using catalytic converters
3) Scrubbing emissions
4) Using renewable energy resources

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15
Q

What do catalytic converters do?

A

1) Convert CO to CO2
2) Oxides of nitrogen are converted to N2 and O2
3) Unburnt hydrocarbons are oxidised to CO2 AND H2O

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16
Q

Under what conditions do alkanes react with halogens?

A

UV light.

17
Q

If chlorine is mixed methane what will be produced?

A

Chloromethane, dichloromethane, trichloromethane and tetrechloromethane.

18
Q

Write out the equations for the reactions listed above.

A

CH4 + Cl2 –> CH3Cl + HCl etc etc .

19
Q

What is the mechanism for the monohalogenation of alkanes called? What are the conditions?

A

Free radical photochemical substitution.

UV light

20
Q

What is the iniation reaction? Give an example with chlorine. What is it an example of ?

A

Molecule –> Radicals
UV light
Cl2 ——————-> 2Cl• Homolytic fission

21
Q

What is the propagation reaction? Continue with the previous example.

A

Molecule + radical –> radical + molecule
CH4 + Cl• –> CH3• + HCl and
CH3• + Cl2 –> CH3Cl + Cl•

22
Q

What is the termination reaction? Continue

A

2 radicals –> Molecule
Cl• + Cl• –> Cl2
CH3• + Cl• –> CH3Cl
CH3• + CH3• –> C2H6