Alkanes Flashcards

1
Q

What is a homologous series

A

Organic compounds with the same functional group and each successive member cdiffers by CH2

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2
Q

What is a functional group

A

Part of a compound responsible for chemical reactions

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3
Q

What is saturated?

A

Hydrocarbon with single bonds only

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4
Q

What is a hydrocarbon

A

A compound containing hydrogen and carbon atoms only

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5
Q

Alkanes and cycloalkanes general formula

A

CnH2n+2
CnH2n

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6
Q

What is a sigma bond

A

Bond formed by the lengthways overlap of orbitals directly between two bonding atoms

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7
Q

What structure is alkanes

A

Form a tetrahedral structure with a bond angle of 109.5 degrees
4 bonding pairs of electrons repel equally

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8
Q

What to add in alkanes script about London forces

A

more surface area contact

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9
Q

What happens with more branching

A

more branching –> reduces s.a. contact –> weakened London forces –> decreased M.P. / B.P.

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10
Q

Complete combustion vs incomplete combustion

A

Alkane + oxygen –> carbon dioxide / carbon monoxide OR carbon + water

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11
Q

How to use combustion equations

A

Write out combustion equation using volume ratios
Simplify ratios
Work out n
Balance and work out N

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12
Q

What is homolytic fission?

A

A covalent bond is broken and each of the bonded atoms receives on electron to form two radicals

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13
Q

What is a free radical

A

Reactive species with an unpaired electron

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14
Q

What is the condition and reagent

A

UV light
Halogen molecule

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15
Q

What is the overall equation

A

alkane + halogen –> halogenated alkane + hydrogen halide

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16
Q

Go through steps

A

Initiation: halide dies
1st propagation: using alkane + radical formed in hydrogen, the radical formed steals a hydrogen
2nd propagation: bring the radical formed back down + other reactant (halogen that didnt split)
- every side of every propagation has exactly one radical
Termination: two radicals combining to make a neutral molecule

17
Q

What is preferred

A

Structural formula rather than simply a molecular formula