Alkanes Flashcards
Most importance spurce of alkane
Petroleum
Components of natural gas
Methane 70-90%, ethane propane, butane and trace amounts of CO2, HS, N, Helium
Natural gas and petroleum are known as
Fossil fuel
As the molecular size of alkanes increases, its dispersion force also ____
Increases
For compounds in homologous series, the larger the MW, The _____ the bp due to increase in dispersion forces
Higher
For compounds with the same MW, the larger the surface are, the ____ the boiling point
Higher
Reactions in alkane
Combustion and Halogenation
Oxidation in alkane results in
____ C-Z where Z can usually be Oxygen, and ____ in C-H
Increase of CO and decrease of CH
Reduction in alkanes results in ____ of CH and the ___ of CO
Increase, decrease
This occur in presence of heat or light converting alkanes to alkyl halides
Halogenation
The reaction is a radical substitution because the X replaces H by radical intermediate
Halogenation of alkanes
______ forms mixture of products
Chlorination
____ is selective and often form major or one product
Bromination
In this step, the bond cleavage forms two radicals
Initiation
One radical reacts and a new radical is formed
Propagation