Alkanes Flashcards

1
Q

What are alkanes

A

Alkanes are a homologous series made up of saturated molecules which are joined by sigma bonds/single covalent bonds

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2
Q

are alkanes unreactive

A

yes

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3
Q

what is the general formula for alkanes

A

Cn H2n+2

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4
Q

what is a sigma bond

A

​its a single covalent bond ​formed when​ two orbitals overlap end-to-end

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5
Q

what is a covalent bond

A

a shared pair of electrons

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6
Q

in an alkane how many sigma bonds does each carbon atom have?

A

4

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7
Q

each bond angle is

A

109.5 degrees (tetrahedral)

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8
Q

how is crude oil seperated into fractions

A

fractional distillation

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9
Q

why do the boiling points of alkanes increase?

A

London forces hold molecules together in solids and liquids but once broken the molecules move apart and the alkane becomes a gas. The greater the intermolecular forces the higher the boiling point.

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10
Q

If the chain length increases will the surface contact increase

A

Yes

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11
Q

Do you need more or less energy to overcome the greater london forces

A

more

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12
Q

Isomers of alkanes have the same molecular mass true or false

A

true

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13
Q

Do branched isomers have higher or lower boiling points than straight-chained isomers?

A

Lower

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14
Q

What are the factors that make alkanes unreactive?

A

-The C-C and C-H sigma bonds are strong
-The C-C bonds are non-polar
-The elecronegativity of carbon and hydrogen is so similar that it is considered non-polar

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15
Q

What do all alkanes react with?

A

A plentiful supply of oxygen to produce carbon dioxide and water

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16
Q

What is combustion?

A

It is a chemical reaction that involes burning the organic compounds

17
Q

what do all combustion reactions give out?

A

heat

18
Q

What are 3 reasons alkanes are used as fuels?

A

-They are readily available
-Easy to transport
-Burn in plentiful supply of oxygen without releasing toxic products

19
Q

What is carbon monoxide?

A

A colourless odourless highly toxic gas

20
Q

When does incomplete combustion occur?

A

When there is a limited supply of oxygen usually in a closed system.

21
Q

What happens in the presence of sunlight (UV)

A

alkanes react with halogens

22
Q

3 stages of the mechanism

A

initiation,propagation and termination

23
Q

What happens in initiation?

A

the covalent bond in a halogen molecule is broken by homolytic fission. Each halogen atom takes one electorn from the pair forming two highly reactive molecules

24
Q

What happens in propagation?

A

In the first step a halogen radical reacts with a C-H bond forming an alkyl radical and a molecule of hydrogen something

In the second step each alkyl radical reacts with another halogen molecule to form..

Then the new halogen radical reacts with another alkane and it goes on and on.

25
Q

What happens in termination?

A

two radicals colide to form molecules with all electrons paired

26
Q

What is further substitution

A

different possible monosubstitutes