Alkanes Flashcards

1
Q

What are alkanes

A

Alkanes are saturated aliphatic hydrocarbons. Alkanes are represented by the general formula CnH2n+2 where
n can be 1,2,3,4… etc

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2
Q

Alkanes are also known as_____

A

paraffins

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3
Q

_____ is an oily, thick inflammable and usually dark coloured
liquid.

A

Petroleum

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4
Q

Separating the crude

petroleum into useful components is called _____

A

refining

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5
Q

The first step in

refining is_____

A

fractional distillation

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6
Q

what is the catalyst used in bergius process

A

Iron

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7
Q

What is Fischer-Tropsch process

A

The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen or water gas into liquid hydrocarbons

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8
Q

What is octane number

A

Octane number is a measure of the quality of gasoline: the higher the
octane number, the better the fuel.

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9
Q

The quality of diesel fuel is expressed in terms of a

number called_____

A

cetane number

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10
Q

Physical properties of alkanes

A

1) Alkanes are colourless and odourless.
2) They possess weak Van Der Waals forces of attraction.
3) Alkanes having 1-4 carbon atoms are gases, then from 5-17 carbon atoms they are liquid and alkanes having 18 or more carbon atoms are solid at 298K.

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11
Q

Alkane molecules are very weakly polar or nonpolar because
there is very little ——————-difference between the carbon
and hydrogen atoms.

A

electro negativity

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12
Q

Boiling point of alkanes ———- with the increase in the length
of the carbon chain

A

increases

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13
Q

Branching in the carbon chain —————- the boiling point

A

decreases

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14
Q

Alkanes are soluble in —————– solvents

A

nonpolar

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15
Q

Define halogenation

A

It is defined as the replacement of hydrogen atom(s), from an
alkane molecule, by halogen atom(s)

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16
Q

What is pyrolysis

A

This is a process of decomposing an organic substance by heating it to
high temperature in the absence of oxygen.
When an alkane is heated to a high temperature (at about 875 K),
it decomposes into small molecules. This process is known as
pyrolysis.

17
Q

Features of Alkanes

A

1) Alkanes are nonpolar compounds.
2) Their physical constants like
boiling point, density, etc., increase with the increase in the number
of carbon atoms.
3) Branching in the chain decreases the boiling
point

18
Q

Methods for preparing alkanes

A
Alkanes are prepared by: 
(i) Wurtz reaction, 
(ii) Kolbe’s electrolytic method
(iii) hydrogenation of unsaturated hydrocarbons, 
(iv) decarboxylation of carboxylic acids; 
(v) reduction of alkyl
halides, 
(vi) hydrolysis of Grignard reagents.
19
Q

When alkanes with six or more carbon atoms are heated under
pressure in the presence of a catalyst, _____ are
produced.

A

aromatic hydrocarbons

20
Q

The main reaction of alkanes is _____

A

combustion; heat for power

production is its chief outcome.