ALKANES Flashcards
other name for alkanes
parrafins
the reaction alkanes undergo
free radical subst rxn
what are the steps of FRS rxn
1- inititaion
2- propagation
3- termination
define inititaion
Cl radicals formed
define propagation
ch3cl radical formed, Hcl formed
temination
1- cl cl radicals react and terminate the chain
2- ch3cl ch3cl radicals terminate
3- ch3cl and cl radicals combine and terminate
2 types of cracking, definition of cracking
thermal and catalytic, long chain hydrocarbons converted to short chain (alkenes) and useful HCs
thermal cracking
1- high temp high press, 750 C temp
2-cracks upto 8th carbon atom
catalytic cracking
1- high temp catalyst
2- takes place in presence of zeolites
3-cracking of more than 8 C atoms
uses of cracking
- to meet supply and demand
- ethene production
- get Hydrogen for ammonia production
reforming
long chain hydrocarbons converted to branched chain and cyclic HCs
reforming condt
500 C temp, 40 atm press, Al2O3 catalyst
another rxn for alkanes
combustion
combustion 2 types
in excess o2, producing co2 and h20
in limited o2, producing co and h20 and carbon soot
formula for combustion
CxHy + x+y/4O2 —-> xCO2 + y/2 H2O
X= no. of C atoms Y= no. of H atoms