Alkali metal Flashcards
atomic radius down the group (group 1)
increases
density down the group (group 1)
increases
exception - Na > K
flame color of Li (group 1)
chrimson red
flame color of Na (group 1)
yellow
flame color of K (group 1)
violet
flame color of Rb (group 1)
red-violet
flame color of Cs (group 1)
blue
electronegativity down the group (group 1)
decreases
electron affinity down the group (group 1)
decreases
metallic bond strength down the group (group 1)
decreases
in s block, minimum S.R.P. is of (group 1)
lithium
in s block, maximum S.R.P. is of (group 1)
sodium
hydration energy is proportional to (group 1)
charged density
which of the elements can be used as electrodes in photoelectric cell (group 1)
Cs and K
why are alkali metals very reactive (group 1)
because of low I.E. , they tend to form ionic bond faster by fajan’s rule
general element formed on reaction in air (group 1)
N2: Lithium nitride only
O2: OXIDE, PEROXIDE AND SUPEROXIDE
forms normal oxide on reaction with O2 (group 1)
Li
forms peroxide on reaction with O2 (group 1)
Na
forms superoxide on reaction with O2 (group 1)
K, Rb, Cs
which have highest hydration energy (group 1)
Li
Li shows diagonal relationship with (group 1)
Mg
general compound on reaction with H2 (group 1)
MH
ionic salt like hydride
general compound on reaction with halogen (group 1)
MX
it forms ionic compound but lithium halides are somewhat covalent due to fajan’s rule
reactivity with H2O down the group (group 1)
decreases
reducing nature down the group (group 1)
increases
exception - lithium has maximum
reacts least rapidly with H2O (group 1)
Li
Due to High MP
MP and BP down the Group (group 1)
Decreases
liq NH3+ alkali metal (group 1)
Blue colour solution
paramagnetic
both of this is due to ammoniated electrons
why do the solution become bronze in colour on standing (group 1)
blue colour disappears as the electrons forms amide
solution losses its e- thus it also looses the paramagnetic property of the solution and become diamagnetic
Al + Li is used in (group 1)
Aircraft
Li + Mg is used for (group 1)
Armour
white metals are (group 1)
alloys of Li
White metals are used in (group 1)
ball bearings for motor engines
Na + Pb alloy is used in
anti knock additives in petrol
what act as an liquid coolent in fast breeding nuclear reactor (group 1)
Liq Na
absorbs CO2 (group 1)
KOH
used in soaps (group 1)
KOH, NaOH
potassium soaps are softer for skin than the sodium soaps.
Lithium shows anomalous behavior because (Group 1)
- small size
2. high polarizing power
The bicarbonate salts (Group 1)
solid except LiHCO3
M2CO3 on heating (Group 1)
Li : Li2O +CO2
Na, K , Rb , Cs : no reaction
LiNO3 heat (Group 1)
Li2O + NO2
NaNO3 500 C (Group 1)
NaNO2 +O2
NaNO3 800 C (Group 1)
NaNO2 + N2 +O2