Alkali - Aggregate Reaction Flashcards
4 stages of alkali aggregate reaction
1) Aggregates react with alkalis in cement (in pore fluids)
2) Forms hydroscopic gel
3) Gel takes on water - expands
4) Cracks
What do you need for alkali aggregate reaction?
Alkali in pore fluids
Reactive silica in aggregate
Water
What happens if there is excess alkali?
Expansion is limited
What happens is there is excess silica?
All hydroxyls mopped up by reactive silica limiting expansion
Sources of alkali (5)
PC - sodium oxide
Pozzolanic - PFA GGBS
Chemical admixtures - super plasticisers, water reducers, retarders
Water
Aggregates unlikely unless from marine environment
Sources of silica (3)
Aggregates
PC - consumed by hydration reaction
Pozzolanic - PFA, GGBS. Majority consumed by reaction with PC
Types of aggregate that are sources of silica (4)
Low - limestone
Normal - flint
High - greywake
V High - calcined flint
Features of alkali -aggregate reaction (4)
Surface cracks 2- 3 years
Extrudations - silica gel at surface
Surface pop outs - local
Disintegration
Factors for alkali - aggregate reaction (4)
Alkali - PC
Silica - aggregate type
Moisture -fuels reaction
Temp
Combating alkali - aggregate reaction (4)
Limit alkali
Pozzolanic eg PFA - dilution effect
Limit moisture
Limit silica - avoids types of aggregates
Tests for alkali aggregate reaction
Mortar bar test - assesses aggregate alkali silica reactivity
BS812123 38 degree moist air 52 weeks - measures expansion