Aliphatic Compounds Flashcards

1
Q

Alkane —> Haloalkane

A

X2, UV Light

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2
Q

Haloalkane —> Nitrile

A

NaCN or KCN, ethanol, reflux

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3
Q

Haloalkane —> Amine

A

Excess Ethanolic Ammonia (or amines), heat

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4
Q

Haloalkane —> Alcohol

A

Warm NaOH or KOH, H2O, Reflux

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5
Q

Alcohol —> Haloalkane

A

NaX, H2SO4

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6
Q

Alcohol —> Ester

A

Carboxylic Acid, Conc. Acid Catalyst, Heat

Or Acyl Choride or Acid Anhydride

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7
Q

Primary Alcohol —> Aldehyde

A

Acidified Potassium Dichromate, Distillation

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8
Q

Primary Alcohol —> Carboxylic Acid

A

Acidified Potassium Dichromate, Reflux

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9
Q

Secondary Alcohol —> Ketone

A

Acidified Potassium Dichromate, Reflux

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10
Q

Alcohol —> Alkene

A

Conc. H2SO4 or H3PO4 catalyst, 170 Degrees

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11
Q

Alkene –> Alcohol

A

Steam, H3PO4(s) catalyst, 300 Degrees, 60-70atm

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12
Q

Alkene –> Haloalkane

A

HX

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13
Q

Alkene –> Alkane

A

H2, Ni Catalyst, 150 Degrees

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14
Q

Alkene –> Dihaloalkane

A

X2

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15
Q

Nitrile –> Amine

A

LiAlH4 then Dilute acid

Or H2, Ni Catalyst, High Temp and Pressure

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16
Q

Nitrile –> Carboxylic Acid

A

Dilute HCl, Reflux

17
Q

Aldehyde –> Carboxylic Acid

A

Acidified Potassium Dichromate, Reflux

18
Q

Aldehyde –> Hydroxynitrile

A

HCN

19
Q

Aldehyde –> Primary Alcohol

A

NaBH4 then H2O

20
Q

Ketone –> Hydroxynitrile

A

HCN

21
Q

Ketone –> Secondary Alcohol

A

NaBH4 then H2O

22
Q

Hydroxynitrile –> Carboxylic Acid

A

Dilute HCL, Reflux

23
Q

Hydroxynitrile –> Amine

A

LiAlH4 then Dilute acid

Or H2, Ni Catalyst, High Temp and Pressure

24
Q

Carboxylic Acid –> Ester

A

Alcohol, Conc. Acid Catalyst, Heat

25
Q

Carboxylic Acid –> Acyl Chloride

A

SOCl2

26
Q

Acyl Chloride –> Carboxylic Acid

A

Cold H2O

27
Q

Acyl Chloride –> Primary Amide

A

NH3

28
Q

Acyl Chloride –> Secondary Amide

A

Primary Amine

29
Q

Acyl Chloride –> Ester

A

Alcohol

30
Q

Ester –> Carboxylic Acid

A

Dilute Acid, Reflux

31
Q

Ester –> Carboxylate Salt

A

Dilute Alkali, Reflux

32
Q

Ester –> Alcohol

A

Dilute Acid or Alkali, Reflux